Isopentyltriphenylphosphonium Bromide 异戊基三苯基溴化鏻
CAS 28322-40-9 MFCD00031594
化学结构图
SMILES: [Br-].CC(C)CC[P+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1
化学属性
| Mol. Formula | (CH3)2CHCH2CH2P(C6H5)3Br |
|---|---|
| Mol. Weight | 415.35 |
| Melting Point | 157-159 °C(lit.) |
| TSCA | No |
别名和识别编码
| Chemical Name | Isopentyltriphenylphosphonium Bromide |
|---|---|
| Synonym | (3-Methylbutyl)triphenylphosphonium bromide Isoamyltriphenylphosphonium bromide 三苯基溴化膦异戊酯 |
| MDL Number | MFCD00031594 |
| PubChem Substance ID | 24861526 |
| CAS Number | 28322-40-9 |
| EC Number | 248-966-4 |
| Beilstein Registry Number | 3804221 |
| Chemical Name Translation | 异戊基三苯基溴化鏻 |
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分类
- {SNA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents
相关文献及参考
- 1. Kongkathip, B.; et al. Steroids 75 , 834, (2010) 摘要
- 2. Ghosal, P.; et al. Tetrahedron 66 , 7504, (2010)
- 3. Mai, E.; Schneider, C. Chem. Eur. J. 13 , 2729, (2007) 摘要
- Beil. 16 ,IV,183
- FT-IR 2 (2), 3328:B / FT-NMR 1 (2), 1668:A / RegBook 1 (2), 2273:B / Structure Index 1 , 355:A:8
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
