Trimethylsilyl Acetate 三甲基硅乙酸酯
CAS 2754-27-0 MFCD00008695
信息真实价格透明
资金保障
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信息真实价格透明
资金保障
专业采购外包团队在线服务
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现货库存
一流品牌服务
分类
- {uni_hamburg} no charge; ester; 1fragment
- Building Blocks, C2 to C5, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks
- {SA} Building Blocks, C2 to C5, Carbonyl Compounds, Chemical Synthesis, Esters, Organic Building Blocks
相关文献及参考
- Short: III/35F
- Beilstein:4(4)4003
- Lithiation and acylation give the TMS esters of ß-keto acids, which can be converted to the unstable ß-keto acids themselves, or directly to methyl ketones: Synth. Commun., 13, 183 (1983).
- Short: III/35E
- Has been used in a 2-carbon homologation sequence for the synthesis of (E)-alkenoic acids via silyl ketene acetals: J. Org. Chem., 63, 8785 (1998):
安全信息
GHS Symbol
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- P305+P351+P338+P337+P313
- P332+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
- P370+P378
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
- R11 Highly flammable 非常易燃
其他信息
- 蒸气压:35 mm Hg ( 30 °C)
- Acros Organics:三甲基硅乙酸酯 Trimethylsilyl acetate, 97%(2754-27-0)
- MOL 文件:2754-27-0.mol
- 三甲基硅乙酸酯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 A1567 乙酸三甲基硅酯 Trimethylsilyl Acetate 25ML 299元 2014/06/02 A1567 乙酸三甲基硅酯 Trimethylsilyl Acetate 250ML 1630元 2010/06/21 391980250 三甲基硅乙酸酯 Trimethylsilyl acetate 97% 25 GR 270元
- 图谱信息:三甲基硅乙酸酯(2754-27-0)质谱(MS)
- 和水反应。
- TCI Shanghai:乙酸三甲基硅酯 Trimethylsilyl Acetate,>;98.0%(GC)(2754-27-0)
- 蒸气密度:1 (vs air)
- Sigma Aldrich:2754-27-0(sigmaaldrich)
- F:10-21
- Alfa Aesar:乙酸三甲基硅酯,98% Trimethylsilyl acetate, 98%(2754-27-0)
- 敏感性:Moisture Sensitive
- TSCA:Yes