Methoxycarbonylsulfenyl Chloride 甲氧羰基磺酰氯
CAS 26555-40-8 MFCD00013648
化学结构图
SMILES: COC(=O)SCl
化学属性
| Mol. Formula | C2H3ClO2S |
|---|---|
| Mol. Weight | 126.55 |
| Refractive index | 1.4770 to 1.4880 |
| Boiling Point | 69°C/75mmHg(lit.) |
| Density | 1.399 g/mL at 25 °C(lit.) |
| Flash Point | 54°C(lit.) |
| TSCA | No |
别名和识别编码
| Chemical Name | Methoxycarbonylsulfenyl Chloride |
|---|---|
| Synonym | Methoxycarbonyl-sulfensäurechlorid thiocarbonic acid, anhydrosulfide with methyl thiohypochlorite 甲氧基羰基磺酰氯 Carbonothioic acid anhydrosulfide with thiohypochlorus acid, O-methyl ester Carbonothioic acid, anhydrosulfide with thiohypochlorous acid, methyl ester (methoxycarbonyl)sulfenyl chloride S-氯 O-硫代碳酸甲酯 Methoxycarbonylsulfenyl chloride Methoxycarbonyl-sulfenylchlorid Methoxycarbonylsulphenyl chloride thiocarbonic acid, anhydrosulphide with methyl thiohypochlorite Thiohypochlorous acid anhydrosulfide with O-methyl thiocarbonate |
| CAS Number | 26555-40-8 |
| PubChem Substance ID | 87572957 |
| EC Number | 247-801-3 |
| Beilstein Registry Number | 1849908 |
| MDL Number | MFCD00013648 |
| Reaxys-RN | 1849908 |
| Chemical Name Translation | 甲氧羰基磺酰氯 |
信息真实价格透明
资金保障
专业采购外包团队在线服务
信息真实价格透明
资金保障
专业采购外包团队在线服务
品牌质保精细包装
现货库存
一流品牌服务
分类
- {SA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfenyl Halides, Sulfur Compounds
相关文献及参考
- Beil. 3 ,IV,279
- FT-IR 2 (1), 977:D / FT-NMR 1 (1), 931:A / RegBook 1 (1), 695:K / Structure Index 1 , 105:B:7
- Short: II/2 Title: Magnetic Properties of Coordination and Organometallic Transition Metal Compounds Author: König, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/2 Year: 1966 ISBN: 3-540-03593-1 ISBN: 978-3-540-03593-0 Internet Resource: DOI:10.1007/b19948 RefComment: 170 figs., XII, 578 pages. Hardcover Abstract: The data compiled refer to susceptibility measurements (susceptibility, Curie-constants, magnetic moments, transition temperatures) and ESR-measurements (g-factors and other parameters of the applied spin Hamiltonian). In volume II/2 the literature from 1899 up to 1964 has been considered. Volume II/8 supplements volume II/2, taking into account the data on magnetic susceptibilities and ESR parameters published in the p eriod 1964 to 1968. The following subvolumes II/10,II/11, II/12 supplement data up to 1974.
- Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
- Reacts with arenes under Friedel-Crafts conditions to give S-aryl thiocarbonates, thus providing a method for the introduction of the thiol group into an aromatic ring: Z. Chem., 17, 411 (1977).
- Reagent for the preparation of unsymmetrical disulfides, by successive reaction with different thiols: Helv. Chim. Acta, 56, 1370 (1973):
- Reaction of the same intermediate with KO-t-Bu provides a route to trisulfides. Cyclic trisulfides can also be prepared: J. Org. Chem., 44, 4144 (1979).
安全信息
GHS Symbol
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H226 Flammable liquid and vapour 易燃液体和蒸气
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338+P310
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P301+P330+P331+P310
- P303+P361+P353
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P370+P378
- P304+P340
- P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
- P304+P340+P310
- P403+P235
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P301+P330+P331
- P241+P242+P243
- P305+P351+P338
- P303+P361+P353+P310+P363
- R10 Flammable 易燃
- R34 Causes burns 会导致灼伤
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
