(R)-(2,2-Dimethyl-1,3-Dioxolan-4-Yl)Methyl 4-Methylbenzenesulfonate (R)-2,2-二甲基-1,3-二氧戊环基-4-甲基苯磺酸甲酯

CAS 23788-74-1 MFCD00063233

化学结构图

23788-74-1
SMILES: Cc1ccc(S(=O)(=O)OC[C@H]2COC(C)(C)O2)cc1

化学属性

Mol. FormulaC13H18O5S
Mol. Weight286.34
Refractive indexn20/D 1.506(lit.)
Density1.208 g/mL at 25 °C(lit.)
Melting Point41-43 °C(lit.)

别名和识别编码

Chemical Name(R)-(2,2-Dimethyl-1,3-Dioxolan-4-Yl)Methyl 4-Methylbenzenesulfonate
Synonym 1,2-异亚丙基-sn-甘油 3-甲苯磺酸酯 1,2-异亚丙基-sn-甘油 3-甲苯磺酸酯 D-α,β-异亚丙基甘油-γ-甲苯磺酸酯 1,2-异亚丙基-sn-甘油 3-甲苯磺酸酯 D-α,β-异亚丙基甘油-γ-甲苯磺酸酯 (R)-2,2-二甲基-1,3-二氧戊环-4-甲基对甲苯磺酸酯 1,2-异亚丙基-sn-甘油 3-甲苯磺酸酯 D-α,β-异亚丙基甘油 γ-甲苯磺酸酯 (R)-(-)-对甲基苯磺酸-2,2-二甲基-1,3-二氧戊环基-4-甲酯 D-α,β-异亚丙基甘油-γ-甲苯磺酸酯 (R)-(-)-2,2-二甲基-1,3-二氧环戊基-4-甲醇对甲基苯磺酸酯
CAS Number23788-74-1
PubChem Substance ID87568971
Beilstein Registry Number19(5)2,373
MDL NumberMFCD00063233
Reaxys-RN89800
Chemical Name Translation(R)-2,2-二甲基-1,3-二氧戊环基-4-甲基苯磺酸甲酯
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分类

  • Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks, Protected Alcohols
  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks, Protected Alcohols

相关文献及参考

  • 1. C. André et al. Tetrahedron Asymmetry 9 , 1359, (1998)
  • 2. K.C. Nicolaou et al. J. Chem. Soc., Chem. Commun. , 349, (1984)
  • 3. S.K. Bhatia, J. Hajdu Tetrahedron Lett. 28 , 1729, (1987)
  • Beil. 19 ,V,2,373

安全信息

GHS Symbol
WGK Germany3
Hazard Codes Xi
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P332+P313
  • P305+P351+P338+P337+P313
  • P302+P350
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P337+P313
  • P302+P352+P332+P313+P362+P364
Signal word Warning
Storage condition 0-10 0-10°C
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Protected Alcohols - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Protected Alcohols - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Dioxanes & Dioxolanes
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Polyols 多元醇

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