1,2-Bis[(2R,5R)-2,5-Diethylphospholano]Benzene(1,5-Cyclooctadiene)Rhodium(I) Tetrafluoroborate (SP-4-3)-苄基双(三苯基膦)氯化钯
CAS 228121-39-9 MFCD01862464
化学结构图
SMILES: [Rh+].CC[C@@H]1CC[C@@H](CC)P1C1C=CC=CC=1P1[C@@H](CC[C@H]1CC)CC.F[B-](F)(F)F.C1C[CH][CH]CC[CH][CH]1 |^1:32,33,36,37|
化学属性
| Mol. Formula | C30H48BF4P2Rh |
|---|---|
| Mol. Weight | 660.36 |
| Appearance | red-orange xtl. |
| Stability | air sensitive |
别名和识别编码
| Chemical Name | 1,2-Bis[(2R,5R)-2,5-Diethylphospholano]Benzene(1,5-Cyclooctadiene)Rhodium(I) Tetrafluoroborate |
|---|---|
| Synonym | (R,R)-Et-DUPHOS-Rh [(R,R)Ethyl-DuPhosRh(COD)]BF4 1,2-双[(2R,5R)-2,5-二乙基膦烷基]苯(1,5-环辛二烯)四氟硼酸铑(I) (R,R)-Et-DUPHOS-Rh [(R,R)Ethyl-DuPhosRh(COD)]BF4 |
| CAS Number | 228121-39-9 |
| Chemical Name Translation | (SP-4-3)-苄基双(三苯基膦)氯化钯 |
| PubChem Substance ID | 329762007 |
| MDL Number | MFCD01862464 |
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分类
- Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, DuPhos/BPE, Privileged Ligands and Complexes
相关文献及参考
- 1. Fox, M. E.; et al., Large-Scale Synthesis of a Substituted D-Phenylalanine Using Asymmetric Hydrogenation Org. Process Res. Dev. 15 , 1163-1171, (2011)
- 2. Sammet, B.; et al., A two step synthesis of a key unit B precursor of cryptophycins by asymmetric hydrogenation Beilstein J. Org. Chem. 7 , 243-245, (2011)
- 3. Chaturvedula, P. V.; et al., Enantioselective synthesis of constrained phenylalanine analogues Tetrahedron Lett. 51 , 5588-5591, (2010)
- 4. Steinhuebel, D. P.; et al., Asymmetric Hydrogenation of Protected Allylic Amines Org. Lett. 12 , 4201-4203, (2010)
- 5. Guo, Y.; et al., A General Approach to the Synthesis of β2-Amino Acid Derivatives via Highly Efficient Catalytic Asymmetric Hydrogenation of α-Aminomethylacrylates Adv. Synth. Catal. 352 , 1539-1553, (2010)
