Dichloro[(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl][(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) 二氯[(S)-(-)-2,2′-二[二(3,5-二甲苯基)膦基]-1,1′-联萘基][(2S)-(+)-1,1-二(4-甲氧苯基)-3-甲基-1,2-丁二胺]钌(II)

CAS 220114-01-2 MFCD09753027

化学结构图

220114-01-2
SMILES: CC(C)[C@H](N)C(N)(C1=CC=C(C=C1)OC)C1=CC=C(C=C1)OC.CC1=CC(C)=CC(=C1)P(C1=CC(C)=CC(C)=C1)C1C=CC2C=CC=CC=2C=1C1=C(C=CC2C=CC=CC1=2)P(C1=CC(C)=CC(C)=C1)C1=CC(C)=CC(C)=C1.Cl[Ru]Cl

化学属性

Mol. FormulaC71H74Cl2N2O2P2Ru
Mol. Weight1221.30
Appearance orange pwdr.
Stabilityair sensitive
RedoxReduction

别名和识别编码

Chemical NameDichloro[(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl][(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II)
Synonym 二氯[(S)-(-)-2,2′-二[二(3,5-二甲苯基)膦基]-1,1′-联萘基][(2S)-(+)-1,1-二(4-甲氧苯基)-3-甲基-1,2-丁二胺]钌(II)
CAS Number220114-01-2
Chemical Name Translation二氯[(S)-(-)-2,2′-二[二(3,5-二甲苯基)膦基]-1,1′-联萘基][(2S)-(+)-1,1-二(4-甲氧苯基)-3-甲基-1,2-丁二胺]钌(II)
PubChem Substance ID253659926
MDL NumberMFCD09753027
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分类

  • Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes

相关文献及参考

  • Matsumura, K.; et al., Chiral ruthenabicyclic complexes: precatalysts for rapid, enantioselective, and wide-scope hydrogenation of ketones J. Am. Chem. Soc. 133 , 10696-10699, (2011)
  • Noyori, R.; et al., Metal-Ligand Bifunctional Catalysis: A Nonclassical Mechanism for Asymmetric Hydrogen Transfer between Alcohols and Carbonyl Compounds J. Org. Chem. 66 , 7931-7944, (2001)
  • Ohkuma, T.; et al., Asymmetric Hydrogenation of Amino Ketones Using Chiral RuCl2(diphosphine)(1,2-diamine) Complexes J. Am. Chem. Soc. 122 , 6510-6511, (2000)
  • Ohkuma, T.; et al., General Asymmetric Hydrogenation of Heteroaromatic Ketones Org. Lett. 2 , 1749-1751, (2000)
  • Pfefferkorn, J. A.; et al., Substituted oxazolidinones as novel NPC1L1 ligands for the inhibition of cholesterol absorption Bioorg. Med. Chem. Lett. 18 , 546-553, (2008)
  • Tellers, D. M.; et al., Enantioselective hydrogenation of an α-alkoxy substituted ketone with chiral ruthenium (phosphinoferrocenyl)oxazoline complexes Tetrahedron Asymmetry 17 , 550-553, (2006)

安全信息

Hazard Codes Xi
WGK Germany3
GHS Symbol
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P308+P311
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H360 May damage fertility or the unborn child 可能对生育能力或未出生婴儿造成伤害
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. BINAPs - Privileged Ligands and Complexes
  1. BINAP
  2. Ruthenium
  1. BINAP
  2. 96-6954 Takasago BINAP Ru Diamine Catalyst Kit
  1. Catalysts
  2. 96-6954 Takasago BINAP Ru Diamine Catalyst Kit
  1. Catalysts
  2. Ruthenium

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