[(R)-(+)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl]palladium(II) chloride [(S)-(-)-2,2′-双(二-对甲苯基膦)-1,1′-联萘]氯化钯(II)
CAS 215597-19-6 MFCD11656205
化学结构图
SMILES: CC1C=CC(=CC=1)P(C1=CC=C2C=CC=CC2=C1C1C2=CC=CC=C2C=CC=1P(C1C=CC(C)=CC=1)C1C=CC(C)=CC=1)C1C=CC(C)=CC=1.Cl[Pd]Cl
化学属性
| Mol. Formula | C48H40Cl2P2Pd |
|---|---|
| Mol. Weight | 856.10 |
| Melting Point | >;300 °C |
别名和识别编码
| Chemical Name | [(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-1,1'-binaphthyl]palladium(II) chloride |
|---|---|
| Synonym | [PdCl2{(S)-4-tolylbinap}] [(R)-(+)-2,2′-双(二-对甲苯基膦)-1,1′-联萘]氯化钯(II) [(S)-(-)-2,2′-双(二-对甲苯基膦)-1,1′-联萘]氯化钯(II) |
| MDL Number | MFCD11656205 |
| CAS Number | 215597-19-6 |
| Chemical Name Translation | [(S)-(-)-2,2′-双(二-对甲苯基膦)-1,1′-联萘]氯化钯(II) |
| PubChem Substance ID | 329762823 |
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分类
- {SNA} Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes
- Asymmetric Synthesis, BINAPs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes
相关文献及参考
- 1. Lautens, M.; Hiebert, S., Scope of Palladium-Catalyzed Alkylative Ring Opening J. Am. Chem. Soc. 126 , 1437-1447, (2004)
- 2. Bruyere, D.; et al., New developments in the Pd-catalyzed cyclization-coupling reaction of alkene-containing carbonucleophiles with organic halides (and triflates). The first examples of asymmetric catalysis. J. Organomet. Chem. 687 , 466-472, (2003)
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- H315 Causes skin irritation 会刺激皮肤
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H319 Causes serious eye irritation 严重刺激眼睛
- H302+H312+H332
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
