CAS 213697-53-1 MFCD02183572-2-Dicyclohexylphosphino-2'-(N,N-dimethylamino)biphenyl 2-二环己膦基-2'-(N,N-二甲胺)-联苯 TAO{mole}

2-Dicyclohexylphosphino-2'-(N,N-dimethylamino)biphenyl 2-二环己膦基-2'-(N,N-二甲胺)-联苯

CAS 213697-53-1 MFCD02183572

化学结构图

SMILES: CN(C)c1ccccc1-c1ccccc1P(C1CCCCC1)C1CCCCC1

化学属性

Mol. Formula	C26H36NP
Mol. Weight	393.54
Melting Point	121-124 °C(lit.)
TSCA	No
Appearance	白色晶体
Solubility	Insoluble
Stability	对空气敏感

别名和识别编码

Chemical Name	2-Dicyclohexylphosphino-2'-(N,N-dimethylamino)biphenyl
CAS Number	213697-53-1
Alfabeta Name	DICYCLOHEXYLPHOSPHINODIMETHYLAMINOBIPHENYL NN22()-----,'
MDL Number	MFCD02183572
Synonym	2-Dicgclohexylphosphino-2’-(N,N-dimethylamino)biphenyl 2-Dicyclohexylphosphino-2'-(N, 2-二环己基磷-2-(N,N-二甲基氨基)联苯 2-双环己基膦-2'-(N,N-二甲基氨基)联苯,98% DAVEPHOS 2-(Dicyclohexylphosphino)-2'-(N,N-dimethylamino)biphenyl,98%DavePhos 2-二环己基磷-2-（N,N-二甲基氨基）联苯 2-(DICYCLOHEXYLPHOSPHINO)-2'-(DIMETHYLAMINO)BIPHENYL [1,1''-BIPHENYL]-2-AMINE, 2''-(DICYCLOHEXYLPHOSPHINO)-N,N-DIMETHYL- Davep 2-二环己膦基-2′-(N,N-二甲胺)联苯 DavePhos 2-二环己基膦-2′-(N, N-二甲胺基)联苯 2-(N,N-Dimethylamino)-2-(dicyclohexylphosphino)biphenyl 2-二环己膦基-2'-(N,N-二甲胺)-联苯 2-二环己基膦-2'-(N,N-二甲胺)-联苯 2-Dicyclohexylphosphino-2'-(dimethylamino)biphenyl 2-DICYCLOHEXYLPHOSPHINO-2'-(N,N-DIMETHY& 2-Dicyclohexylphosphino-2'-(N,N-dimethylamino)- 2-DICYCLOHEXYLPHOSPHINO-2'-(N,N-DIMETHYLAMINO)BIPHENYL
PubChem Substance ID	2734217
Chemical Name Translation	2-二环己膦基-2'-(N,N-二甲胺)-联苯
Reaxys-RN	8649190
LabNetwork Molecule ID	LN00119019
InChI	InChI=1S/C26H36NP/c1-27(2)25-19-11-9-17-23(25)24-18-10-12-20-26(24)28(21-13-5-3-6-14-21)22-15-7-4-8-16-22/h9-12,17-22H,3-8,13-16H2,1-2H3

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品牌质保精细包装现货库存一流品牌服务

产品应用

用于钯催化 C-N 键形成的有效配体；含羟基、酰胺或烯醇酮的芳基卤的胺?化反应。
钯催化 Suzuki 芳基-芳基偶联反应的配体，生成苯并二噁庚英。

安全信息

Warnings AIR SENSITIVE

WGK Germany3

GHS Symbol

Precautionary statements

P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P332+P313
P305+P351+P338+P337+P313
P302+P350
P337+P313
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P305+P351+P338
P302+P352+P332+P313+P362+P364

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激

Signal word Warning

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S37 Wear suitable gloves 戴适当手套；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R22 Harmful if swallowed 吞咽有害

Storage condition 储存温度2-8℃ Air Sensitive

Hazard Codes Xi Xi,Xn

其他信息

上游原料:乙酸乙酯 --> 乙醚 --> 四氢呋喃 --> 二氯甲烷 --> 氢氧化铵 --> 硫酸二甲酯 --> 碘甲烷 --> 镁 --> 三氯化磷 --> 氯化亚铜 --> 二乙胺 --> 环己烷 --> 1,2-二溴乙烷 --> 2-氯苯胺 --> 对溴甲苯 --> 氯代环己烷 --> 溴代环己烷 --> 2-溴氯苯 --> 2-溴苯胺 --> 3,5-二甲基溴苯
Sigma Aldrich:213697-53-1(sigmaaldrich)
存储注意事项:空气敏感;氮气保护
TCI Shanghai:2-(二环己膦基)-2'-(N,N-二甲胺)联苯 2-(Dicyclohexylphosphino)-2'-(dimethylamino)biphenyl,>;98.0%(LC)(213697-53-1)
检测方法:GC
Acros Organics:2-二环己基磷-2-（N,N-二甲基氨基）联苯 2-Dicyclohexylphosphino-2'-(N,N-dimethylamino)biphenyl, 97%(213697-53-1)
敏感性:Air Sensitive
2-二环己膦基-2'-(N,N-二甲胺)-联苯价格(试剂级):更新日期产品编号产品名称包装价格 2011/04/16 D3389 2-(二环己膦基)-2'-(N,N-二甲胺)联苯 2-(Dicyclohexylphosphino)-2'-(dimethylamino)biphenyl 1G 1270元 2011/04/16 D3389 2-(二环己膦基)-2'-(N,N-二甲胺)联苯 2-(Dicyclohexylphosphino)-2'-(dimethylamino)biphenyl 5G 4830元 2010/06/21 356230050 2-二环己膦基-2'-(N,N-二甲胺)-联苯 2-Dicyclohexylphosphino-2'-(N,N-dimethylamino)biphenyl 97% 5 GR 13361元
Alfa Aesar:2-双环己基膦-2'-(N,N-二甲基氨基)联苯,98% 2-Dicyclohexylphosphino-2'-(N,N-dimethylamino)biphenyl, 98%(213697-53-1)
用途二:精细化工原料，医药中间体。
用途一:作为配体，用于Suzuki, Buchwald等偶联反应以及取代反应中
MOL 文件:213697-53-1.mol