(S)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole (S)-5,5'-双(二苯基膦)-4,4'-二-1,3-苯并二茂
CAS 210169-54-3 MFCD09753005
化学结构图
SMILES:
化学属性
| Mol. Formula | C38H28O4P2 |
|---|---|
| Mol. Weight | 610.57 |
| Melting Point | 231-235 °C |
| Appearance | off-white pwdr. |
别名和识别编码
| Chemical Name | (S)-5,5'-Bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole |
|---|---|
| Synonym | (R)-(+)-5,5′-双(二苯基膦)-4,4′-二-1,3-苯并二噁茂 [4(R)-(4,4′-二-1,3-苯并二噁茂)-5,5′-二基]双[二苯基膦] (S)-(-)-5,5′-双(二苯基膦)-4,4′-二-1,3-苯并二噁茂 (S)-SEGPHOS® |
| MDL Number | MFCD09753005 |
| CAS Number | 210169-54-3 |
| Chemical Name Translation | (S)-5,5'-双(二苯基膦)-4,4'-二-1,3-苯并二茂 |
| Reaxys-RN | 11841467 |
| PubChem Substance ID | 329761551 |
信息真实价格透明
资金保障
专业采购外包团队在线服务
信息真实价格透明
资金保障
专业采购外包团队在线服务
品牌质保精细包装
现货库存
一流品牌服务
分类
- Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, SEGPHOS
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, SEGPHOS
相关文献及参考
- Gao, X.; et al., Enhanced anti-Diastereo- and Enantioselectivity in Alcohol-Mediated Carbonyl Crotylation Using an Isolable Single Component Iridium Catalyst J. Org. Chem. 76 , 2350-2354, (2011)
- Guo, X.-X.; et al., Rhodium-catalyzed enantioselective alkynylative cyclization of allenyl aldehydes with terminal alkynes Tetrahedron Asymmetry 21 , 1730-1736, (2010)
- Maeda, T.; et al., Diastereo- and Enantioselective Hydrogenation of α-Amino-β-Keto Ester Hydrochlorides Catalyzed by an Iridium Complex with MeO-BIPHEP and NaBArF: catalytic Cycle and Five-Membered Chelation Mechanism of Asymmetric Hydrogenation Chem. Eur. J. 16 , 11954-11962, (2010)
- Miura, T.; et al., Nickel-Catalyzed Denitrogenative Annulation Reactions of 1,2,3-Benzotriazin-4(3H)-ones with 1,3-Dienes and Alkenes J. Org. Chem. 75 , 5359-5362, (2010)
- Ogaki, S.; et al., Enantioselective Synthesis of Axially Chiral Hydroxy Carboxylic Acid Derivatives by Rhodium-Catalyzed [2 + 2 + 2] Cycloaddition J. Org. Chem. 76 , 1926-1929, (2011)
- Suda, T.; et al., Rhodium-Catalyzed Asymmetric Formal Olefination or Cycloaddition: 1,3-Dicarbonyl Compounds Reacting with 1,6-Diynes or 1,6-Enynes Angew. Chem. Int. Ed. Engl. 50 , 4475-4479, (2011)
