N,N-Dimethyltrimethylsilylamine N,N-二甲基三甲基硅胺

CAS 2083-91-2 MFCD00008297

化学结构图

2083-91-2
SMILES: CN(C)[Si](C)(C)C

化学属性

Mol. Formula(CH3)3SiN(CH3)2
Mol. Weight117
Density0.732
Refractive index1.3960 to 1.3980
Flash Point-19°C(lit.)
TSCAYes
Boiling Point86°C
Solubility分解
Melting Point<0°C

别名和识别编码

Chemical NameN,N-Dimethyltrimethylsilylamine
Synonym N-Methyl-N-(trimethylsilyl)methylamine {Chemicalbook} 二甲基氨基三甲基硅烷 N-TRIMETHYLSILYDIMETHYLAMINE N,N-DIMETHYLAMINOTRIMETHYLSILANE N,n-Pentamethylsilanamine TMSDMA (Dimethylamino)trimethylsilane~N-(Trimethylsilyl)dimethylamine (DIMETHYLAMINO)TRIMETHYLSILANE N-(三甲基硅基)二甲胺 N-(三甲基硅基)二甲胺 TMSDMA 二甲基氨基三甲基硅烷 Silanamine,pentamethyl- N-(Trimethylsilyl)-dimethylamin N,N-二甲基三甲基硅胺 {Chemi CD5400 trimethylsilyldimethylamine
MDL NumberMFCD00008297
CAS Number2083-91-2
EC Number218-222-3
Beilstein Registry Number1731861
PubChem Substance ID87576488
Reaxys-RN1731861
Chemical Name TranslationN,N-二甲基三甲基硅胺
InChIKeyKAHVZNKZQFSBFW-UHFFFAOYSA-N
LabNetwork Molecule IDLN00226786
InChIInChI=1S/C5H15NSi/c1-6(2)7(3,4)5/h1-5H3
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Derivatization Reagents, Nitrogen Compounds, Organic Building Blocks, Protected Amines, Silylation Reagents, 分析/色谱, 分析试剂
  • {SNA} Analytical/Chromatography, Ion Sensor Materials, Silanizing Agents for ISE
  • {SNA} Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Protected Amines
  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Reagent for siliylation of a wide range of functional groups, without the need for added base, useful for amino acids: J. Chromat. Sci., 7, 704 (1969). In the presence of the hindered ligand 2-(Di-tert-butyl­phosphino)­biphenyl­, L19758, Pd-catalyzed cross-coupling reactions with aryl halides to give substituted N,N-dimethylanilines have been effected: Chem. Commun., 1976 (2004).
  • Short: II/25D
  • Short: III/20a

安全信息

Packing GroupII
UN Number 2733
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R11 Highly flammable 非常易燃
Safety Statements
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Storage condition Moisture Sensitive Flammables area
GHS Symbol
WGK Germany3
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P370+P378
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Hazard Codes F,C
Hazard Class3/8

其他信息

  • 图谱信息:N,N-二甲基三甲基硅胺(2083-91-2)核磁图( 13 CNMR) N,N-二甲基三甲基硅胺(2083-91-2)核磁图( 1 HNMR) N,N-二甲基三甲基硅胺(2083-91-2)红外图谱(IR1)
  • MOL 文件:2083-91-2.mol
  • 敏感性:Moisture Sensitive
  • 下游产品:三(二甲胺基)膦
  • TCI Shanghai:N,N-二甲基三甲基硅胺 N-(Trimethylsilyl)dimethylamine,>;95.0%(GC)(2083-91-2)
  • Alfa Aesar:N-(三甲基硅基)二甲胺,96% N-(Trimethylsilyl)dimethylamine, 96%(2083-91-2)
  • F:1-10
  • N,N-二甲基三甲基硅胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30231880 N,N-二甲基三甲基硅胺 10ml 297元 2011/04/16 T0591 N-(三甲基硅烷基)二甲胺 N-(Trimethylsilyl)dimethylamine 25ML 639元 2010/06/21 209970100 N,N-二甲基三甲基硅胺 N,N-Dimethyltrimethylsilylamine 97% 10 ML 383元
  • Sigma Aldrich:2083-91-2(sigmaaldrich)
  • Acros Organics:N,N-Dimethyltrimethylsilylamine, 97%(2083-91-2)
  • TSCA:Yes

系列性分类


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