CAS 20439-47-8 MFCD00062985-(1R,2R)-(-)-1,2-Diaminocyclohexane 左旋-反式-1,2-环己二胺 TAO{mole}

(1R,2R)-(-)-1,2-Diaminocyclohexane 左旋-反式-1,2-环己二胺

CAS 20439-47-8 MFCD00062985

化学结构图

SMILES: N[C@@H]1CCCC[C@H]1N

化学属性

Mol. Formula	C6H14N2
Mol. Weight	114.19
Flash Point	70°(158°F)
TSCA	No
Boiling Point	78°C/13mmHg(lit.)
Melting Point	41
Density	0.931
Stability	对空气敏感
Solubility	miscible
Refractive index	n20/D 1.49(lit.)

别名和识别编码

Chemical Name	(1R,2R)-(-)-1,2-Diaminocyclohexane
CAS Number	20439-47-8
Synonym	(R,R)-1,2-DIAMINOCYCLOHEXANE 1,2-二氨基环己烷, MIXTURE OF ISOMERS (1R)-TRANS-1,2-DIAMINOCYCLOHEXANE (1R,2R)-(-)-1,2-二氨基环己烷;1,2-环已二胺;左旋-反式-1,2-环己二胺 (1R)-TRANS-1,2-CYCLOHEXANEDIAMINE (1R)-(-)-TRANS-1,2-DIAMINOCYCLOHEXANE (-)-(R,R)-1,2-DIAMINOCYCLOHEXANE (R,R)-(-)-1,2-DIAMINOCYCLOHEXANE 左旋-反式-1,2-环己二胺 (1R,2R)-(-)-1,2-DIAMINOCYCLOHEXANE (1R,2R)-(-)-1,2-二氨基环己烷 (1R,2R)-(-)-1,2-CYCLOHEXANEDIAMINE (R,R)-DACH 环己二胺 (1R,2R)-CYCLOHEXANE-1,2-DIAMINE 1,2-CYCLOHEXANEDIAMINE 1,2-环己二胺 ########
PubChem Substance ID	87566448
Beilstein Registry Number	13(3)6
MDL Number	MFCD00062985
Reaxys-RN	2801643
EC Number	250-023-7
Chemical Name Translation	左旋-反式-1,2-环己二胺
InChIKey	SSJXIUAHEKJCMH-UHFFFAOYSA-N
LabNetwork Molecule ID	LN00007212
InChI	InChI=1S/C6H14N2/c7-5-3-1-2-4-6(5)8/h5-6H,1-4,7-8H2/t5-,6-/m1/s1

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产品应用

Can be used as a building block for chiral ligands.

安全信息

GHS Symbol

WGK Germany3

Hazard statements

H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤

Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

Hazard Codes C

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P330+P331
P301+P330+P331+P310
P303+P361+P353+P310+P363
P304+P340
P304+P340+P310
P305+P351+P338
P305+P351+P338+P310
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word

UN Number 3259

Safety Statements

S24 Avoid contact with skin 避免皮肤接触；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；

Risk Statements

Storage condition 储存温度2-8℃,密封保存 2-8°C 对空气敏感，密封保存。 Air Sensitive

Packing GroupIII

Hazard Class8

RTECSGU8749500

Warnings 危险化学品

其他信息

毒性分级:中毒
可燃性危险特性:明火可燃
下游产品:奥沙利铂
类别:有毒物品
F:34
Sigma Aldrich:694-83-7(sigmaaldrich)
用途一:奥沙利铂中间体。
海关编码:29213099
急性毒性:口服-大鼠 LDL0: 1000 毫克/ 公斤
MSDS 信息:1,2-二氨基环己烷(694-83-7).msds
储运特性:库房通风低温干燥; 与食品原料分开储运
图谱信息:1,2-二氨基环己烷(694-83-7)红外图谱(IR1) 1,2-二氨基环己烷(694-83-7)质谱(MS)
Acros Organics:1,2-环已二胺(混有异构体) 1,2-Diaminocyclohexane, tech., mixture of isomers, 90%(694-83-7)
TCI Shanghai:1,2-环己二胺(顺反异构体混合物) 1,2-Cyclohexanediamine (cis- and trans- mixture),>;95.0%(GC)(694-83-7)
1,2-二氨基环己烷价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 D0277 1,2-环己二胺(顺反异构体混和物) 1,2-Cyclohexanediamine (cis- and trans- mixture) 500ML 674元 2014/06/02 D0277 1,2-环己二胺(顺反异构体混和物) 1,2-Cyclohexanediamine (cis- and trans- mixture) 25ML 174元 2010/06/21 158100010 1,2-二氨基环己烷 1,2-Diaminocyclohexane 90%, tech., mixture of isomers 1 KG 1292元
灭火剂:二氧化碳、砂土、泡沫、干粉
MOL 文件:694-83-7.mol
刺激数据:皮肤-兔子 500 毫克/24小时中度
敏感性:Air Sensitive
蒸气压:0.4 mm Hg ( 20 °C)
Alfa Aesar:1，2-二氨基环己烷,mixtureofisomers,99% 1,2-Diaminocyclohexane, mixture of isomers, 99%(694-83-7)
外观性质:无色液体。