Tetraphenylphosphonium Chloride 四苯基氯化鏻
CAS 2001-45-8 MFCD00011916
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分类
- {SNA} Chemical Synthesis, Phase Transfer Catalysts, Phosphonium Salts, Synthetic Reagents
相关文献及参考
- High-temperature phase-transfer catalyst (see Appendix 2). In combination with Bis(acetonitrile)dichloropalladium(II), 10002, provides an effective catalyst for the Heck reaction of normally unreactive aryl halides, e.g. chlorobenzene with styrene to give stilbene. The reaction is performed at 140-150o in DMF or NMP in the presence of sodium acetate. The reaction may be further improved by the addition of 10-12 mol% N,N-Dimethylglycine, A19670: Angew. Chem. Int. Ed., 37, 481 (1998).
- Reagent for Bi and Co.
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352
- P302+P352+P332+P313+P362+P364
- P304+P340
- P305+P351+P338
- P305+P351+P338+P337+P313
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
- P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
- P332+P313
- P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
- P403+P233
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
- S36 Wear suitable protective clothing 穿戴适当的防护服;
- S37 Wear suitable gloves 戴适当手套;
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
其他信息
- Sigma Aldrich:2001-45-8(sigmaaldrich)
- 海关编码:29310095
- MSDS 信息:Tetraphenylphosphonium chloride(2001-45-8).msds
- TCI Shanghai:四苯基氯盐 Tetraphenylphosphonium Chloride,>;98.0%(LC)(T)(2001-45-8)
- F:3-10
- 用途一:医药中间体。
- 四苯基氯化价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1375 四苯基氯化 Tetraphenylphosphonium Chloride 5G 500元 2014/06/02 T1375 四苯基氯化 Tetraphenylphosphonium Chloride 25G 1490元 2010/06/21 204030100 四苯基氯化 Tetraphenylphosphonium chloride 98% 10 GR 930元
- MOL 文件:2001-45-8.mol
- Alfa Aesar:四苯基氯化膦,98% Tetraphenylphosphonium chloride, 98%(2001-45-8)
- 图谱信息:四苯基氯化(2001-45-8)红外图谱(IR1) 四苯基氯化(2001-45-8)核磁图( 1 HNMR) 四苯基氯化(2001-45-8)红外图谱(IR2) 四苯基氯化(2001-45-8)质谱(MS) 四苯基氯化(2001-45-8)核磁图( 13 CNMR)
- Acros Organics:四苯基氯化磷 Tetraphenylphosphonium chloride, 99%(2001-45-8)
- 敏感性:Hygroscopic