Tributyltin Fluoride 三正丁基氟化锡

CAS 1983-10-4 MFCD00013547

化学结构图

1983-10-4
SMILES: CCCC[Sn](F)(CCCC)CCCC

化学属性

Mol. FormulaC12H27FSn
Mol. Weight309.06
Melting Point248-252°
TSCAYes
Flash Point>150°C
Solubility不溶于水,溶于多数有机溶剂。
Density1,28 g/cm3

别名和识别编码

Chemical NameTributyltin Fluoride
Synonym Tributylstannane fluoride FLUOROTRI-N-BUTYLTIN TRIBUTYLTIN FLUORIDE, POLYMER tri-n-butyltinfluoridepowder Stannane, tributylfluoro- Fluorotri-n-butyltin TRI-N-BUTYLFLUOROTIN BioMeT TBTF 氟三丁基锡 TRIBUTYLTIN FLUORIDE Tin, tributyl-, fluoride Fluorotributyltin 三正丁基氟化锡聚合物 CBL 9B Tributyltin(IV) fluoride 氟化三丁锡 TRI-N-BUTYLTIN FLUORIDE STANNANE,FLUOROTRIBUTYL- 三丁锡氟化物 Tributylin Triflouride (as Fl) Tributylfluorostannane Tributyltin fluoride 三正丁基氟化锡 tributylfluorotin polymer 三丁基锡氟化物 Fluorotributylstannane 三丁基氟化锡 Tributylfluorotin(IV)
Beilstein Registry Number4125568
PubChem Substance ID16120
CAS Number1983-10-4
EC Number217-847-9
Reaxys-RN14371904
MDL NumberMFCD00013547
Chemical Name Translation三正丁基氟化锡
Wiswesser Line NotationF-SN-4&4&4
LabNetwork Molecule IDLN00220182
InChIInChI=1S/3C4H9.FH.Sn/c3*1-3-4-2;;/h3*1,3-4H2,2H3;1H;/q;;;;+1/p-1
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分类

  • {SA} Chemical Synthesis, Others, Solid Supported Synthesis, Specialty Synthesis, Supported Reagents

相关文献及参考

  • 1. Urabe. H.; Kuwajima, I. et. al. Tetrahedron Lett. 24 , 5001, (1983)
  • Fieser 11 ,544
  • Corp MSDS 1 (2), 3400:C / RegBook 1 (2), 3189:B / Structure Index 1 , 508:A:8

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P302+P352+P312+P362+P364
  • P301+P312+P330
  • P337+P313
  • P403+P233
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H301 Toxic if swallowed 吞食有毒
  • H312 Harmful in contact with skin 皮肤接触有害
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H372 Causes damage to organs through prolonged or repeated exposure 长期或频繁接触会损伤器官
  • H302+H312
Hazard Codes T,N T;N
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Signal word Danger
RTECSWH8275000
UN Number UN 3261 8/PG 2 3146 UN3146 2788
Safety Statements
  • S35 This material and its container must be disposed of in a safe way 该物料及其容器必须以安全方式处置;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R25 Toxic if swallowed 吞咽有毒
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R50/53
  • R48/23/25
  • R21 Harmful in contact with skin 与皮肤接触有害
Storage condition Moisture Sensitive
Packing GroupIII
Hazard Class6.1
Warnings 危化品目录(2015) 危险化学品
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 50 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   SAIGBL Sangyo Igaku.  Japanese Journal of Industrial Health.  (Nippon Sangyo
   Eisei Igakkai, Kosu Eisei Bldg., 1-29-8, Shinjuku, Shinjuku-ku, Tokyo 160,
   Japan)  V.1-    1959-  Volume(issue)/page/year: 15,3,1973

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 320 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AECTCV Archives of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   070944)  V.1-    1973-  Volume(issue)/page/year: 14,111,1985

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 60 ug/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 300,5,1993

其他信息

  • 图谱信息:三正丁基氟化锡(1983-10-4)核磁图( 1 HNMR) 三正丁基氟化锡(1983-10-4)核磁图( 13 CNMR) 三正丁基氟化锡(1983-10-4)质谱(MS) 三正丁基氟化锡(1983-10-4)红外图谱(IR2) 三正丁基氟化锡(1983-10-4)红外图谱(IR1)
  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • Alfa Aesar:三正丁基氟化锡 Tri-n-butyltin fluoride(1983-10-4)
  • 灭火剂:二氧化碳、砂土、水、泡沫
  • 毒性分级:高毒
  • MSDS 信息:三丁基氟化锡(1983-10-4).msds
  • 外观性质:白色固体。
  • 三正丁基氟化锡价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/05/25 39602 三正丁基氟化锡 Tri-n-butyltin fluoride 5g 238元 2010/05/25 39602 三正丁基氟化锡 Tri-n-butyltin fluoride 25g 665元 2010/05/25 39602 三正丁基氟化锡 Tri-n-butyltin fluoride 100g 2478元
  • Sigma Aldrich:1983-10-4(sigmaaldrich)
  • 可燃性危险特性:受热分解有毒氟化物气体
  • MOL 文件:1983-10-4.mol
  • 急性毒性:口服-大鼠 LDL0: 320 毫克/公斤
  • TCI Shanghai:三正丁基氟化锡 Tributyltin Fluoride,>;95.0%(W)(1983-10-4)
  • 职业标准:TWA 0.1 毫克 (锡)/立方米; STEL 0.2 毫克 (锡)/立方米
  • TSCA:Yes
  • 敏感性:Moisture Sensitive
  • F:21
  • 类别:有毒物品

系列性分类


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