CAS 1897-45-6 MFCD00045594-2,4,5,6-Tetrachloroisophthalonitrile 2,4,5,6-四氯间苯二甲腈 TAO{mole}

2,4,5,6-Tetrachloroisophthalonitrile 2,4,5,6-四氯间苯二甲腈

CAS 1897-45-6 MFCD00045594

化学结构图

SMILES: N#Cc1c(Cl)c(Cl)c(Cl)c(C#N)c1Cl

化学属性

Mol. Formula	C8Cl4N2
Mol. Weight	266
Flash Point	2 °C
Boiling Point	350
Melting Point	251
Density	1.71
Solubility	微溶于水，溶于丁酮、环己烷、酸。

别名和识别编码

Chemical Name	2,4,5,6-Tetrachloroisophthalonitrile
CAS Number	1897-45-6
Synonym	Tetrachlorobenzene-1,3-dicarbonitrile {uni_hamburg} Kabiguard 164SA {Chem { 1,3-dicyanotetrachlorobenzene Vanox 750PM Tetrachloroisophthalonitrile Kavach 2,4,5,6-四氯邻苯二甲腈霉必清 Chlorthalonil (ISO) tetrachloroisophthalonitrile 2,4,5,6-tetrachloro- Fortur Clortosip 500SC isophthalonitrile, tetrachloro- 百菌清烟剂 2,4,5,6-tetrachloro-1,3-ben Vanox 500SC Tetrachlorisophthalonitril-4-ch Bravo 6F TCIN DACONIL 2787(R) TPN (pesticide) Tetrachlorisophthalonitril 百菌清;四氯间苯二甲腈;四氯间苯二腈;2,4,5,6-四氯邻苯二甲腈 2,4,5,6-tetrachloro-1,3-be TPN DACONIL 2,4,5,6-Tetrachloro-1,3-dicyanobenzene 1,3-Benzenedi-carbonitrile,
MDL Number	MFCD00045594
Beilstein Registry Number	1978326
PubChem Substance ID	87576717
EC Number	217-588-1
Reaxys-RN	1978326
Merck Number	2166
Chemical Name Translation	2,4,5,6-四氯间苯二甲腈
Wiswesser Line Notation	NCR BG CG DG FG ECN
LabNetwork Molecule ID	LN01269000

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分类

{SNA} Alphabetical Index of Analytical Standards, Analytical Standards, Aromatics, C, CH, Chromatography, EPA, Endocrine Disruptors (Draft), Environmental Standards, Fungicides, Method and Regulation Specific, Pesticides, Bactericides, Fungicides and Disinfectants, Standards for Personal Care and Cosmetic Products, prohibited substances (EU-REGULATION No 1223/2009), solutions, 农残和代谢标准品, 农残标准品, 分析/色谱, 按照字母排序
Mutagenesis Research Chemicals
{S
{uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
Agro-Products
{SNA} Additional Standards,
{SNA} Additional Standards, All Fungicides, Analytical Standards, Aromatics, C,

产品应用

百菌清是一种高效低度广谱的杀菌剂，广泛用于防治果树、蔬菜菜叶等多种害虫，对水稻，小麦、棉花等多种害虫，也具有较好的防治效果。也用作工业防霉剂、水果保鲜剂。
校准仪器和装置；评价方法；工作标准；质量保证/质量控制；其他。

安全信息

GHS Symbol

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P305+P351+P338
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P302+P352+P333+P313+P362+P364
P304+P340+P310
P201 Obtain special instructions before use. 使用前获取专门指示。
P501 Dispose of contents/container to..… 处理内容物/容器.....
P405 Store locked up. 上锁保管。
P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
P302+P350
P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。

Hazard statements

H317 May cause an allergic skin reaction 可能导致皮肤过敏
H330 Fatal if inhaled 吸入致命
H335 May cause respiratory irritation 可能导致呼吸道刺激
H351 Suspected of causing cancer 怀疑致癌
H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
H318 Causes serious eye damage 严重伤害眼睛
H332 Harmful if inhaled 吸入有害
H319 Causes serious eye irritation 严重刺激眼睛
H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
H312 Harmful in contact with skin 皮肤接触有害
H302 Harmful if swallowed 吞食有害

WGK Germany3

Signal word

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

Hazard Codes T+;N,N,T+,Xn,F F,Xn T+,N

Safety Statements

S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；

Risk Statements

R11 Highly flammable 非常易燃
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
R26 Very toxic by inhalation 吸入极毒
R36 Irritating to eyes 刺激眼睛
R37 Irritating to respiratory system 刺激呼吸道
R50/53

UN Number 3439 3276

RTECSNT2600000

Packing GroupII

Hazard Class6.1

Storage condition 室温、干燥。室温储存 0-6°C 储存温度2-8℃

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 142 gm/kg/80W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Kidney, Ureter, Bladder - Kidney tumors
REFERENCE :
   NCITR* National Cancer Institute Carcinogenesis Technical Report Series.
   (Bethesda, MD)  No.0-205. For publisher information, see NTPTR*.
   Volume(issue)/page/year: NCI-TR-41,1978

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2500 ug/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Behavioral - muscle contraction or spasticity
REFERENCE :
   INHEAO Industrial Health.  (National Institute of Industrial Health, 6-21-1
   Nagao, Tama-ku, Kawasaki, 213 Japan)  V.1-    1963- Volume(issue)/page/year:
   4,11,1966

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 10 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85ARAE "Agricultural Chemicals," Thomson, W.T., 4 vols., Fresno, CA, Thomson
   Publications, 1976/77 revision  Volume(issue)/page/year: 4,75,1976/1977

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 310 mg/m3/1H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FMCHA2 Farm Chemicals Handbook.  (Meister Pub., 37841 Euclid Ave.,
   Willoughy, OH 44094)  Volume(issue)/page/year: -,C72,1991

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 3700 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   HOEKAN Hokkaidoritsu Eisei Kenkyushoho.  Report of the Hokkaido Institute of
   Public Health.  (Nishi- 12-chome, Kita-19-jo, Kita-ku, Sapporo 060, Japan) 
   No.1-    1951-  Volume(issue)/page/year: 30,53,1980

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Ad

TYPE OF TEST            : Mutation in

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 500 ug/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   10(Suppl 10),1,1987

TYPE OF TEST            : Mutation in mammalian somatic cells
TEST SYSTEM             : Rodent - mouse Lymphocyte
DOSE/DURATION           : 120 ug/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   12,85,1988

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 14690 nmol/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   19,98,1992

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 2 mg/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   10(Suppl 10),1,1987

TYPE OF TEST            : DNA damage
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 50 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 375,205,1997

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Mold - Aspergillus nidulans
DOSE/DURATION           : 800 ug/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE

其他信息

毒性:大鼠急性经口LD 50 >10000mg/kg，小鼠为3700mg/kg；兔急性经皮LD 5
毒性分级:中毒
方法一:氨氧化将间二甲苯以气态状进行反应器，液氨经蒸发预热后进行反应器，空
{Che
灭火剂:干粉、泡沫、砂土
方法一:氨氧化将间二甲苯以气态状进行反应器，液氨经蒸发预热后进行反应器，空气经过滤、换热后进行反应器，使发生氨氧化反应。催化剂为以硅胶为载体V-Cr为主要组分，反应器为流化床。生成的间二苯腈凝华并连续排出，尾气回收过量的氨或直接去三废处理，间二苯腈经离心脱水、干燥后得粗品，含量94%～98%，收率≥90%。精制可采用减压蒸馏、水洗或溶剂提取等方法。氯化间苯二腈经熔融后送入汽化器汽化或直接与部分气流（N2）通过喷嘴雾化进行反应器。氯气经干燥预热后与气态间苯二腈混合，氮气作为稀释气用于间苯二腈汽化或雾化和调节反应物浓度。反应器采用流化床或其他形式，反应后气体经入捕集器，百菌清凝华析出并被连续送出即为产品，收率90%。尾气主要是氯、氯化氢和氮气，可部分循环或全部去尾气回收处理系统。也可采用将液态四氯化碳喷入捕集器中，在与反应气接触后，百菌清凝华析出。四氯化碳则汽化，与尾气一同排出，经进一步冷却至-6℃，四
外观性质:无色无臭结晶。
用途一:属广谱、高效、低毒杀菌剂，用于农作物病害防治
TCI Shanghai:2,4,5,6-四氯-1,3-苯二腈 Tetrachloroisophthalonitrile,>;98.0%(GC)(N)(1897-45-6)
急性毒性:口服- 大鼠 LD50: 10000 毫克/ 公斤; 口服- 小鼠 LD50: 3700 毫克/ 公斤
图谱信息:百菌清(1897-45-6)质谱(MS) 百菌清(1897-45-6)红外图谱(IR2) 百菌清(1897-45-6)核磁图( 13 CNMR) 百菌清(1897-45-6)红外图谱(IR1)
图谱信息:百
MOL 文件:1897-45-6.mol
TCI Shanghai:2,4,5,6-四氯-1,3-苯二腈
用途四:广谱性保护性杀菌剂，对多种作用真菌病害具有预防作用。药效稳定，残效期长。可用于麦类、水稻、蔬菜、果树、花生、茶叶等作物。如麦类赤霉病，用75%可湿性粉剂11.3g/100m 2 ，对水6kg喷雾；蔬菜病害（番茄早疫病、晚疫病、叶霉病、斑枯病、瓜类霜霉病、炭疽病）用75%可湿性粉剂135～150g，对水60～80kg喷雾；果树霜霉病、白粉病，用75%可湿性粉剂75～100g对水30～40kg喷雾；此外还可用于桃腐病、疮痂病，茶炭疽病、茶饼病、网饼病，花生叶斑病，橡胶溃疡病，甘蓝霜霉病、黑斑病，葡萄炭疽病，马铃薯晚疫病，茄子灰霉病，橘子疮痂病。
上游原料:盐酸 --> 氨 --> 氯 --> 二氧化碳 --> 活性炭 --> 苯甲腈 --> 间二甲苯 --> 氟氯菊酯 --> 间苯二甲腈
可燃性危险特性:燃烧产生有毒氮氧化物和氯化物气体
百菌清价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 T0895 四氯间苯二氰 Tetrachloroisophthalonitrile 25G 1100元
用途五:百菌清是一种高效低毒广谱的杀菌剂，广泛用于防治果树、蔬菜菜叶等多种害虫，对水稻、小麦、棉花等多种病害，也具有较好的防治效
蒸气压小于1.3Pa(40℃).在水中溶解度为0.6ppm，在丙酮中卫2g/kg，二甲苯为8g/kg。工业品含量约为98%，在碱和酸性水溶液中以及对紫外光照射，都是稳定的。制剂2.5%，5%颗粒剂，75%可湿性粉剂。
储运特性:库房通风低温干燥; 与食品原料分开储运
注意事项:[1]对鱼毒药液不能污染鱼塘和水域 [2]不能与石硫合剂、波尔多液等碱性农药混用 [3]容易发生药害梨、柿、桃、梅和苹果树等使用浓度偏高会发生药害与杀螟松混用，桃树易发生药害与克螨特、三环锡等混用，茶树会产生药害
类别:农药