Phosphonium, (3-carboxypropyl)triphenyl-, bromide (1:1) (3-丙羧基)三苯基溴化膦
CAS 17857-14-6 MFCD00274196
化学结构图
SMILES: [Br-].OC(=O)CCC[P+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1
化学属性
| Mol. Formula | C22H22BrO2P |
|---|---|
| Mol. Weight | 429 |
| Melting Point | 246.0 to 250.0 deg-C |
| TSCA | No |
| Stability | 易吸潮 |
别名和识别编码
| Chemical Name | Phosphonium, (3-carboxypropyl)triphenyl-, bromide (1:1) |
|---|---|
| Synonym | |
| MDL Number | MFCD00274196 |
| PubChem Substance ID | 87566628 |
| CAS Number | 17857-14-6 |
| Reaxys-RN | 4173599 |
| EC Number | 000-000-0 |
| Beilstein Registry Number | 4173599 |
| Chemical Name Translation | (3-丙羧基)三苯基溴化膦 |
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分类
- {SNA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents
相关文献及参考
- 1. Luo, Y.; et al. Bioorg. Med. Chem. Lett. 21 , 4844, (2011)
- 2. Zhang, Y.-K.; et al. Bioorg. Med. Chem. Lett. 21 , 644, (2011)
- 3. Wube, A. A.; et al. Bioorg. Med. Chem. 19 , 567, (2011)
- 4. Robinson, A.; Aggarwal, V. K. Angew. Chem. Int. Ed. Engl. 49 , 6673, (2010)
- 5. Dylag, M.; et al. Med. Mycol 48 , 373, (2010)
- 6. Zhang, Y.-N.; et al. Bioorg. Med. Chem. 16 , 8697, (2008)
- 7. Fox, M. E.; et al. J. Org. Chem. 70 , 1227, (2005)
- FT-IR 2 (2), 3337:C
安全信息
GHS Symbol
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P302+P352+P332+P313+P362+P364
- P305+P351+P338+P337+P313
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
