Bis(Triphenylphosphine)Copper(I) Borohydride 双(三苯基膦)硼氢化亚铜
CAS 16903-61-0 MFCD00013219
化学结构图
SMILES: [BH4-].[Cu+].C1=CC=CC=C1P(C1C=CC=CC=1)C1C=CC=CC=1.C1=CC=CC=C1P(C1C=CC=CC=1)C1C=CC=CC=1
化学属性
| Mol. Formula | C36H34BCuP2 |
|---|---|
| Mol. Weight | 603 |
| Melting Point | 150 |
| TSCA | No |
别名和识别编码
| Chemical Name | Bis(Triphenylphosphine)Copper(I) Borohydride |
|---|---|
| MDL Number | MFCD00013219 |
| PubChem Substance ID | 87564081 |
| EC Number | 240-951-0 |
| Synonym | Bis(triphenylphosphine)copper(I) tetrahydridoborate 双(三苯基膦)硼氢化铜(I) Bis(triphenylphosphine)copper(I) borohydride |
| CAS Number | 16903-61-0 |
| Reaxys-RN | 14867991 |
| Chemical Name Translation | 双(三苯基膦)硼氢化亚铜 |
| Beilstein Registry Number | 14867991 |
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分类
- {SNA} Borohydrides, Chemical Synthesis, Reduction, Synthetic Reagents
相关文献及参考
- Specific reagent for reduction of acid chlorides to aldehydes: Tetrahedron Lett., 1437 (1978); 975 (1979). Also reduces sulfonylhydrazones to alkanes: Tetrahedron Lett., 4031 (1980), and aryl azides to amines: J. Chem. Res. (Synop.), 17 (1981).
- In the presence of Lewis acids or HCl, reduces carbonyl compounds with good stereo- and chemo-selectivity, e.g. aldehydes in the presence of ketones: Tetrahedron Lett., 22, 675 (1981).
安全信息
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S7/8 Keep container tightly closed and dry 保存在严格密闭容器中，保持干燥；
- S8 Keep container dry 保持容器干燥；
- R15 Contact with water liberates extremely flammable gases 遇水会释放出极端易燃的气体
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- H315 Causes skin irritation 会刺激皮肤
- P231+P232
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- P405 Store locked up. 上锁保管。
- P501a
GHS Symbol
