(S)-2-((Benzyloxy)methyl)oxirane (S)-苄氧甲基环氧乙烷
CAS 16495-13-9 MFCD00054428
化学结构图
SMILES: c1ccc(COCC2CO2)cc1
化学属性
| Mol. Formula | C10H12O2 |
|---|---|
| Mol. Weight | 164.20 |
| Density | 1.072 |
| Refractive index | 1.5160 to 1.5210 |
| Flash Point | >110°(230°F) |
| TSCA | No |
| Boiling Point | 130°/0.1mm |
别名和识别编码
| Chemical Name | (S)-2-((Benzyloxy)methyl)oxirane |
|---|---|
| CAS Number | 16495-13-9 |
| Alfabeta Name | BENZYLOXYMETHYLOXIRANE S2((()))-- |
| Synonym | (S)-苄氧甲基环氧乙烷 苄基 (S)-(+)-缩水甘油基醚 |
| Beilstein Registry Number | 5246494 |
| MDL Number | MFCD00054428 |
| PubChem Substance ID | 87565093 |
| Reaxys-RN | 4244157 |
| Chemical Name Translation | (S)-苄氧甲基环氧乙烷 |
| EC Number | 231-598-3 |
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分类
- Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Epoxides, Organic Building Blocks
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Epoxides, Organic Building Blocks
相关文献及参考
- 1. S. Takano et al. Synthesis , 539, (1989)
- 2. J. Chem. Soc., Chem. Commun. , 1371, (1989)
- 3. S. Takano et al. Tetrahedron Lett. 31 , 3619, (1990)
- 4. R.E. Ireland et al. J. Org. Chem. 55 , 1423, (1990)
- 5. S. Najdi, M.J. Kurth Tetrahedron Lett. 31 , 3279, (1990)
- 6. M. Honda et al. Chem. Pharm. Bull. 39 , 1385, (1991)
- 7. T.M. Avignon et al. Tetrahedron 47 , 7279, (1991)
- 8. B.H. Lipshutz et al. Org. Synth. 69 , 80, (1990)
安全信息
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P405 Store locked up. 上锁保管。
- P201 Obtain special instructions before use. 使用前获取专门指示。
- P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
- P305+P351+P338+P337+P313
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
TYPE OF TEST : Mutation test systems - not otherwise specified ROUTE OF EXPOSURE : Intraperitoneal TEST SYSTEM : Rodent - mouse DOSE/DURATION : 100 mg/kg REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 298,197,1993
TYPE OF TEST : Cytogenetic analysis ROUTE OF EXPOSURE : Intraperitoneal TEST SYSTEM : Rodent - mouse DOSE/DURATION : 100 mg/kg REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 298,197,1993
TYPE OF TEST : Mutation in microorganisms TEST SYSTEM : Bacteria - Salmonella typhimurium DOSE/DURATION : 660 nmol/plate REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 298,197,1993
TYPE OF TEST : Sister chromatid exchange ROUTE OF EXPOSURE : Intraperitoneal TEST SYSTEM : Rodent - mouse DOSE/DURATION : 100 mg/kg REFERENCE : MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 298,197,1993
