4-Fluorobenzylmagnesium chloride 4-氟苄基氯化镁
CAS 1643-73-8 MFCD01319898
化学结构图
SMILES: Fc1ccc(C[Mg]Cl)cc1
化学属性
| Mol. Formula | C7H6ClFMg |
|---|---|
| Mol. Weight | 168.88 |
| Density | 0.910 g/mL at 25 °C(lit.) |
| Boiling Point | 65 °C(lit.) |
| TSCA | No |
别名和识别编码
| Chemical Name | 4-Fluorobenzylmagnesium Chloride |
|---|---|
| CAS Number | 1643-73-8 |
| EC Number | 250-023-7 |
| Beilstein Registry Number | 2384789 |
| MDL Number | MFCD01319898 |
| PubChem Substance ID | 2778244 |
| Synonym | 4-氟苄基氯化镁 溶液 4-氟苄基氯化镁 |
| Chemical Name Translation | 4-氟苄基氯化镁 |
| LabNetwork Molecule ID | LN01323663 |
| InChI | InChI=1S/C7H6F.ClH.Mg/c1-6-2-4-7(8)5-3-6;;/h2-5H,1H2;1H;/q-1;;+2/p-1 |
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分类
- {SNA} Alkyl, Chemical Synthesis, Grignard Reagents, Organometallic Reagents
安全信息
GHS Symbol
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S30 Never add water to this product 切勿将水加入该产品中；
- S20 When using do not eat or drink 使用时，不得进食，饮水；
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
- S33 Take precautionary measures against static discharges 对静电采取预防措施；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
- S8 Keep container dry 保持容器干燥；
- S29 Do not empty into drains 不要排入下水道；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- R11 Highly flammable 非常易燃
- R19 May form explosive peroxides 可能生成易爆的过氧化物质
- R14 Reacts violently with water 遇水会猛烈反应
- R34 Causes burns 会导致灼伤
- R12 Extremely flammable 极端易燃
- R22 Harmful if swallowed 吞咽有害
- R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
- R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331
- P302+P361+P354
- P304+P340
- P305+P351+P338
- P305+P354+P338
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P316
- P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
- P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
- P370+P378
- P403+P235
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H224 Extremely flammable liquid and vapour 极端易燃液体和蒸气
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H302 Harmful if swallowed 吞食有害
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
- H351 Suspected of causing cancer 怀疑致癌
