Bis(tetramethylene)fluoroformamidinium hexafluorophosphate N,N,N',N'-双(四亚甲基)氟代甲脒六氟磷酸盐
CAS 164298-25-3 MFCD02683430
化学结构图
SMILES: FC(N1CCCC1)=[N+]1CCCC1.F[P-](F)(F)(F)(F)F
化学属性
| Mol. Formula | C9H16F7N2P |
|---|---|
| Mol. Weight | 316.20 |
| Melting Point | 154-160 |
| TSCA | No |
别名和识别编码
| Chemical Name | Bis(tetramethylene)fluoroformamidinium hexafluorophosphate |
|---|---|
| Synonym | BTFFH BTFFH 氟代二吡咯烷碳鎓六氟磷酸盐 氟代二吡咯烷碳鎓六氟磷酸盐 BTFFHFluorobis(tetramethylene)formamidinium hexafluorophosphate 双(四亚甲基)氟代甲酰胺六氟磷酸 |
| MDL Number | MFCD02683430 |
| PubChem Substance ID | 57647648 |
| CAS Number | 164298-25-3 |
| Chemical Name Translation | N,N,N',N'-双(四亚甲基)氟代甲脒六氟磷酸盐 |
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分类
- {SNA} Chemical Biology, Chemical Synthesis, Coupling, Peptide Chemistry, Peptide Coupling, Phosphonium/Uronium/Formamidinium, Synthetic Reagents
相关文献及参考
- 1. Ayman El-Faham, et al J. Org. Chem. 6 , 1563-1573, (2006)
- 2. L.A. Carpino, A. El-Faham, Convenient peptide coupling reagent. J. Am. Chem. Soc. 117 , 5401, (1995)
- 3. A. El-Faham Chem. Lett. , 671, (1998)
- L.A. Carpino, A. El-Faham J. Am. Chem. Soc. 117 , 5401, (1995)
- Reagent for peptide coupling via the acyl fluoride, which may be generated in situ without separate isolation, and has been found advantageous for solid-phase synthesis of peptides incorporating sensitive amino acids for which the acid fluoride is of limited stability: Chem. Lett., 671 (1998). For peptide reagents, see Appendix 6.
- Reagent for peptide coupling via the acyl fluoride, which may be generated in situ without separate isolation, and has been found advantageous for solid-phase synthesis of peptides incorporating sensitive amino acids for which the acid fluoride is of limited stability: Chem. Lett., 671 (1998). For peptide reagents, see Appendix 6.
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
