Trifluralin 氟乐灵

CAS 1582-09-8 MFCD00055241

化学结构图

1582-09-8
SMILES: CCCN(CCC)c1c([N+](=O)[O-])cc(C(F)(F)F)cc1[N+](=O)[O-]

化学属性

Mol. FormulaC13H16F3N3O4
Mol. Weight335
Melting Point48.5-49°C
Boiling Point139 ºC
Density0.64
Solubility不溶于水,溶于多数有机溶剂。
Flash Point100 °C

别名和识别编码

Chemical NameTrifluralin solution
CAS Number1582-09-8
Synonym ######## 2,6-Dinitro-N,N-di-n-propyl-4-(trifluoromethyl)aniline 2,6-Dinitro-N,N-di-n-propyl-α,α,α-trifluoro-p-toluidine 2,6-Dinitro-N,N-dipropyl-4- 2,6-Dinitro-N,N-dipropyl-4-(trifluoromethyl)-benzamine 2,6-Dinitro-N,N-dipropyl-4-(trifluoromethyl)-benzamine; 4-(Di-n-propylamino)-3,5-dinitro-1-trifluoromethylbenzene; alpha,alpha,alpha-Trifluoro-2,6-dinitro-N,N-dipropyl-p-toluidine; Agreflan 24; Elancolan; L-36352; Treflam; Treflan; Trifurex; Trilin 4E 2,6-Dinitro-N,N-dipropyl-4-(trifluoromethyl)benzenamine 2,6-din 2,6-dinitro-N,N-dipropyl-4-(trifluoromethyl)benzenamine 2,6-二硝基-N,N-二丙基-4-(三氟甲基)苯胺 4-(Di-n-propylamino)-3,5-din 4-(Di-n-propylamino)-3,5-dinitro-1-(trifluoromethyl)benzene 4-(Di-n-propylamino)-3,5-dinitro-1-trifluoromethylbenzene 4-(Trifluoromethyl)-2,6-dinitro T
PubChem Substance ID5569
EC Number216-428-8
Beilstein Registry Number1893555
MDL NumberMFCD00055241
Chemical Name Translation氟乐灵
Merck Number13,9757
Wiswesser Line NotationFXFFR CNW ENW DN3&3
InChIInChI=1S/C13H16F3N3O4/c1-3-5-17(6-4-2)12-10(18(20)21)7-9(13(14,15)16)8-11(12)19(22)23/h7-8H,3-6H2,1-2H3
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分类

  • {SNA} Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Chromatography, Dinitroaniline, EPA, Endocrine Disruptors (Draft), Environmental Standards, Method and Regulation Specific, Oeko-Tex Standard 100, Pesticides, Q-Z, T, TP - TZ, 农残和代谢标准品, 按照字母排序, 灭草剂
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
  • {SNA} Alphabetical Index of Analytical Standards,
  • {SNA} All Herbicide Stan
  • {SNA} Additional Standards, Analytical Standards, Dinitroaniline, EPA, Endocrine Disruptors (Draft), Method and Regulation Specific, Oeko-Tex Standard 100,

产品应用

  • 优良的旱田除草剂。

相关文献及参考

  • Merck:13,9757
  • Short: EINECS
  • Short: IV/8A
  • Goldenthal, et al.: Toxicol. Appl. Pharmacol., 18, 185 (1971),
  • Robens, J.F., et al.: Vet. Hum. Toxicol., 22, 328 (1980),

安全信息

GHS Symbol
WGK Germany2
Hazard Codes T,N Xi,N Xi;N,N,Xi,Xn,F Xi;N Xn,N F,Xn
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H330 Fatal if inhaled 吸入致命
  • H332 Harmful if inhaled 吸入有害
  • H351 Suspected of causing cancer 怀疑致癌
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter dust mask type N95 (US), Eyeshields, Faceshields, Gloves
RTECSXU9275000
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P203
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P301+P312
  • P301+P317
  • P302+P352
  • P304+P340
  • P304+P340+P312
  • P305+P351+P338
  • P308+P313
  • P308+P316
  • P309+P311
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
  • P316
  • P318
  • P319
  • P320 Specific treatment is urgent (see … on this label). 紧急具体治疗(见本标签上的)。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P333+P313
  • P333+P317
  • P337+P313
  • P337+P317
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger Warning
Safety Statements
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S46 If swallowed, seek medical advice immediately and show this container or label 食入时,立即求医并出示容器/标签;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S2 Keep out of the reach of children 避免儿童触及;
  • S37 Wear suitable gloves 戴适当手套;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S24 Avoid contact with skin 避免皮肤接触;
Risk Statements
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R50/53
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R22 Harmful if swallowed 吞咽有害
  • R23 Toxic by inhalation 吸入有毒
  • R36 Irritating to eyes 刺激眼睛
  • R11 Highly flammable 非常易燃
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
UN Number UN 2588 2588
Storage condition APPROX 4°C 室温储存 储存温度2-8℃
TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 340 gm/kg/78W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
   Liver - tumors
REFERENCE :
   NCITR* National Cancer Institute Carcinogenesis Technical Report Series.
   (Bethesda, MD)  No.0-205. For publisher information, see NTPTR*.
   Volume(issue)/page/year: NCI-TR-34,1978

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2600 ug/kg/39D-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Blood - lymphoma, including Hodgkin's disease
   Tumorigenic - tumors at site of application
REFERENCE :
   PATHAB Pathologica.  (Via Alessandro Volta, 8 Casella Postale 894, 16128
   Genoa, Italy)  V.1-    1908-  Volume(issue)/page/year: 73,707,1981

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2600 ug/kg/39D-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Blood - lymphoma, including Hodgkin's disease
   Tumorigenic - tumors at site of application
REFERENCE :
   PATHAB Pathol

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 180 gm/kg/78W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
   Liver - tumors
REFERENCE :
   NCITR* National Cancer Institute Carcinogenesis Technical Report Series.
   (Bethesda, MD)  No.0-205. For publisher information, see NTPTR*.
   Volume(issue)/page/year: NCI-TR-34,1978

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 5 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)/page/year: -,604,1986

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1930 mg/kg
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - mydriasis (pupillary dilation)
   Behavioral - somnolence (general depressed activity)
   Skin and Appendages - hair
REFERENCE :
   FCTOD7 Food and Chemical Toxicology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.20-    1982- Volume(issue)/page/year:
   30,1031,1992

TYPE OF TEST            : LC

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >5 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   WRPCA2 World Review of Pest Control.  (London, UK)  V.1-10, 1962-71.

TYPE OF TEST            : LD50 - Le

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 4600 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   BECTA6 Bulletin of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   07094)  V.1-    1966-  Volume(issue)/page/year: 20,554,1978

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 1 mg/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 8(Suppl
   7),1,1986

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 1 mg/L
REFERENCE :
   BSIBAC Bolletino della Societe Italiana di Biologia Sperimentale.  (Casa
   Editrice Idelson, Via A. de Gasperi, 55, 80133 Naples, Italy)  V.2- 1927- 
   Volume(issue)/page/year: 60,2149,1984

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 2 ppm
REFERENCE :
   PATHAB Pathologica.  (Via Alessandro Volta, 8 Casella Postale 894, 16128
   Genoa, Italy)  V.1-    1908-  Volume(issue)/page/year: 73,707,1981

TYPE OF TEST            : DNA damage
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 5 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  V

TYPE OF TEST            : Sex chromosome loss and nondisjunction
TEST SYSTEM             : Mold - Neurospora crassa
DOSE/DURATION           : 1 mg/L
REFERENCE :
   EVHPAZ EHP, Environmental Health Perspectives.  (U.S. Government Printing
   Office, Supt of Documents, Washington, DC 20402)  No.1-    1972-
   Volume(issue)/page/year: 31,75,1979

TYPE OF TEST            : Dominant lethal test

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 160 ug/L
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 7,1,1985

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUT

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 10 gm/kg
SEX/DURATION            : female 6-15 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Newborn - stillbirth
REFERENCE :
   TJADAB Teratology, The International Journal of Abnormal Development. (Alan
   R. Liss, Inc., 41 E. 11th St., New York, NY 10003)  V.1-    1968-
   Volume(issue)/page/year: 23,33,1981

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 200 mg/kg
SEX/DURATION            : male 1 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Fertility - pre-implantation mortality (e.g. reduction in
   number of implants per female; total number of implants per corpora lutea)
   Reproductive - Effects on Embryo or Fetus - cytological changes (including
   somatic cell genetic material)
   Reproductive - Effects on Embryo or Fetus - fetal death
REFERENCE :
   EESADV Ecotoxicology and Environmental Safety.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802)  V.1-    1977-  Volume(issue)/page/year:
   4,263,1980

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 21800 mg/kg
SEX/DURATION            : multigeneration
TOXIC EFFECTS :
   Reproductive - Fertility - litter size (e.g. # fetuses per litter; measured
   before birth)
   Reproductive - Effects on Newborn - growth statistics (e.g.%, reduced weight
   gain)
REFERENCE :
   FCTOD7 Food and Chemical Toxicology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.20-    1982- Volume(issue)/page/year:
   30,1031,1992

其他信息

  • 用途二:属芽前除草剂,用于防除棉花、饲用豆类田一年生杂草
  • 储运特性:库房通风低温干燥; 与食品原料分开储运
  • 注意事项:[1]大豆田播前施用该药,应在播前5-7天施药 [2]低温干旱地区,持效期较长,下茬不宜种高粱、谷子等敏感作物
  • 类别:农药
  • 可燃性危险特性:燃烧产生有毒氮氧化物和氟化物气体
  • 毒性分级:中毒
  • 用途:氟乐灵适用于大豆、棉花、玉米、小麦、旱稻、甘蔗、甜菜、向日葵、番茄、甘蓝、菜豆、胡萝卜、芹菜、香菜等40多种作物及果园、林业苗圃、花卉、草坪、种植 园等防除稗草、野燕麦、狗尾草、马唐、牛筋草、碱茅、千金子、早熟禾、看麦娘、藜、苋、繁缕、猪毛菜、宝盖草、马齿苋等一年生禾本科杂草及部分双子叶杂草。大豆于播前5~7天土壤处理,立即交叉混土5~7厘米深。用药量根据土壤有机质含量不同而异,一般每公顷用48%氟乐灵乳油1.5~3升。与灭草猛、嗪草酮、甲羧除草醚等除草剂混用,可互补不足,扩大杀草谱,提高作物安全性。油菜、花生、芝麻、棉花、十字花科蔬菜等作物田使用,应在播前或苗前施药。不可在百合科、菊科、茄科、葫芦科、藜科蔬菜的直播育苗田中应用,对移载蔬菜番茄、茄子、柿子椒、甘蓝、菜花等,应在移载前或移载后杂草出苗前使用,在移载黄瓜田,待苗高10~15厘米上架时方可作土壤处理,移栽芹菜、洋葱、沟葱、老根韭菜,缓苗后可应用。冬小麦在浇冻水前处理。葡萄、苹果等种植园,春季松土后,杂草
  • 毒性:大鼠急性经口LD 50 >10000mg/kg,小鼠为5000mg/kg,狗>2000mg/kg,家兔急性经皮LD 50 >2000mg/kg;以2000mg/kg剂量喂养大鼠2年,未见不良影响。对鱼类毒性较在,鲤鱼LC 50 为4.2mg/L (48h),金鱼为0.59mg/L,蓝鳃鱼为0.058mg/L。蜜蜂致死量为24mg/只。
  • 用途三:广谱的旱地芽前除草剂。可用于棉花、大豆、豌豆、油菜、花生、土豆、冬小麦、大麦、蓖麻、
  • 急救治疗:尚无特效解毒剂。若摄入量大,病人十分清醒,可用吐根糖浆诱吐,还可在服用的活性炭泥中加入山梨醇。
  • 用途四:优良的旱田除草剂。主要用于棉花、大豆、花生、向日葵、甘蓝、辣椒、豆类、果园等,也可用于麦地和旱稻田,防除一年生禾本科和种子繁殖的多所生杂草和某些阔叶杂草,如稗草、狗尾草、马唐、看麦娘、蟋蟀草、千金子、早熟禾、雀麦、野燕麦、雀舌草、藜、苋、粟米草、繁缕、地肤、马齿苋等。对龙葵、苍耳、苘麻等宿根性多年生杂草防效差或基本无效。对成株杂草无效。高梁、谷子等敏感作物不能使用;甜菜、番茄、马铃薯、黄瓜等抗
  • 上游原料:硝酸 --
  • MSDS 信息:氟乐灵(1582-09-8).msds
  • 用途五:优良的旱田除草剂。主要用于棉花;大豆;花生;向日葵;甘蓝;辣椒;豆类;果园等,也可用于麦地和旱稻田,防除一年生禾本科和种子繁殖的多所生杂草和某些阔叶杂草,如稗草;狗尾草;马唐;看麦娘;蟋蟀草;千金子;早熟禾;雀麦;野燕麦;雀舌草;藜;苋;粟米草;繁缕;地肤;马齿苋等。对龙葵;苍耳;苘麻等宿根性多年生杂草防效差或基本无效。对成株杂草无效。高梁;谷子等敏感作物不能使用;甜菜;番茄;马铃薯;黄瓜等抗性不强,又能用作移栽田。合世界年消费量达万吨及水平。
  • Sigma Aldrich:1582-09-8(sigmaaldrich)
  • 用途一:用作水果、棉花、大豆等多种作物的除草剂
  • 方法一:4-三氟甲基-2,4-二硝基氯苯的制备 甲苯经催化制得氯甲苯,再在光催化下通氯,制得对氯三
  • 外观性质:纯度为98% 是橙黄色结晶,有芳香气味。
  • 产品特性:选择性芽前二硝基苯胺类除草剂。商品名特福力、氟特力。密封保存稳定期为3年。能与大多数农药混配。对高等动物低毒,对家兔眼睛、皮肤有刺激作用。作用机制
  • 产品特性:选择性芽前二硝基苯胺类除草剂。商品名特福力、氟特力。密封保存稳定期为3年。能与大多数农药混配。对高等动物低毒,对家兔眼睛、皮肤有刺激作用。作用机制 对已出土杂草无效。施药后要立即混土 ,在温暖潮湿的土壤中,按推荐药量,药效长8~12周。

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