Ruthenium Carbonyl 十二羰基三钌
CAS 15243-33-1 MFCD00011209
化学结构图
SMILES: [Ru].[Ru].[Ru].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
化学属性
| Mol. Formula | C12O12Ru3 |
|---|---|
| Mol. Weight | 639.33 |
| Melting Point | 150 |
| Solubility | Sparingly soluble in hydrocarbons (e.g. hexane, cyclohexane, benzene) and acetone. Solutions undergo some decomposition on strong heating |
| TSCA | Yes |
| Appearance | orange xtl. |
别名和识别编码
| Chemical Name | Ruthenium Carbonyl |
|---|---|
| Synonym | Triruthenium Dodecacarbonyl {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { |
| MDL Number | MFCD00011209 |
| PubChem Substance ID | 87558750 |
| CAS Number | 15243-33-1 |
| EC Number | 239-287-4 |
| Reaxys-RN | 14281346 |
| Chemical Name Translation | 十二羰基三钌 |
| InChIKey | NQZFAUXPNWSLBI-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN00239128 |
| Canonical SMILES | [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Ru]1[Ru][Ru]1 |
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分类
- {SA} CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Ru Catalysts, Ruthenium, Vapor Deposition Precursors
- {SNA} CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Micro/NanoElectronics, Ru Catalysts, Ruthenium, Ruthenium Catalysts,
- {SNA} CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Micro/NanoElectronics, Ru Catalysts, Ruthenium, Ruthenium Catalysts, Vapor Deposition Precursors, 材
产品应用
- 羰基团的前提和H-转移催化剂。用于芳香族硝基复合物至氨基甲酸盐的还原性羰基化。
相关文献及参考
- Short: III/35D5
- On heating under pressure with norbornene and CO, alkynes undergo aromatization to give condensed hydroquinones: Organometallics, 17, 766 (1998). For reaction scheme, see 2-Hexyne, B22405.
- 1,6-Enynes undergo cyclocondensation with CO under pressure, to give bicyclo[3.3.0]octenones: J. Org. Chem., 62, 3762 (1997):
- FT-IR 2 (3), 4592:B / FT-IR 1 (2), 1299:D / RegBook 1 (2), 3143:B
安全信息
GHS Symbol
- H228 Flammable solid 易燃固体
- H332 Harmful if inhaled 吸入有害
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352+P312+P362+P364
- P304+P340+P312
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
- R11 Highly flammable 非常易燃
- R20 Harmful by inhalation 吸入有害
- R23 Toxic by inhalation 吸入有毒
其他信息
- Sigma Aldrich:15243-33-1(sigmaaldrich)
