4-Acetamido-2,2,6,6-tetramethylpiperidine 4-乙酰氨-2,2,6,6-四甲基哌啶
CAS 14691-89-5 MFCD00043593
化学结构图
SMILES: CC(=O)NC1CC(C)(C)N([O])C(C)(C)C1 |^1:10|
化学属性
| Mol. Formula | C11H21N2O2 |
|---|---|
| Mol. Weight | 213 |
| Melting Point | 143 |
| TSCA | Yes |
| Density | 1.422 |
别名和识别编码
| Chemical Name | 4-Acetamido-2,2,6,6-tetramethylpiperidine |
|---|---|
| MDL Number | MFCD00043593 |
| Beilstein Registry Number | 3546225 |
| CAS Number | 14691-89-5 |
| EC Number | 423-840-3 |
| Reaxys-RN | 11322085 |
| PubChem Substance ID | 87562806 |
| Synonym | 4-乙酰氨-2,2,6,6-四甲基哌啶-1-氧 4-乙酰氨-2,2,6,6-四甲基哌啶-1-氧，自由基 |
| Chemical Name Translation | 4-乙酰氨-2,2,6,6-四甲基哌啶 |
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分类
- {SA} Chemical Synthesis, Radical Chemistry, Stable Radicals, Synthetic Reagents, TEMPO Derivatives
- {SNA} Electron Spin Resonance (ESR/EPR) Spectroscopy, Spectroscopy, Spin Labels, 分析/色谱, 分析试剂
- Chemical Synthesis, Radical Chemistry, Stable Radicals, Synthetic Reagents, TEMPO Derivatives
相关文献及参考
- In the presence of an acid disproportionates to the oxoammonium salt, a highly selective reagent for alcohol oxidation. For a review of oxoammonium (nitrosonium) salts, see: Heterocycles, 27, 509 (1988); for a brief feature on oxoammonium salts, see: Synlett, 1757 (2003). In combination with tosic acid, oxidizes alcohols to aldehydes and ketones: J. Org. Chem., 56, 6110 (1991). For oxidation of diols to ɑ-dicarbonyl compounds, see: J. Org. Chem., 59, 6338 (1994). Review of the use of stable nitroxyl radicals for the oxidation of primary and secondary alcohols: Synthesis, 1153 (1996) Cf also 4-Hydroxy-TEMPO, A12497, and TEMPO, A12733. .
安全信息
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H302 Harmful if swallowed 吞食有害
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P302+P352+P332+P313+P362+P364
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P332+P313
- P305+P351+P338+P337+P313
- P302+P350
- P337+P313
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S22 Do not breathe dust 不要吸入粉尘；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R22 Harmful if swallowed 吞咽有害
