(+)-Tröger’s base
CAS 14645-24-0 MFCD00151116
化学结构图
SMILES: CC1=CC2C[N@@]3C[N@@](CC4C=C(C)C=CC3=4)C=2C=C1
化学属性
| Mol. Formula | C17H18N2 |
|---|---|
| Mol. Weight | 250.34 |
| Melting Point | 127-131 °C(lit.) |
别名和识别编码
| Chemical Name | (+)-Tröger’s base |
|---|---|
| Synonym | (5R,11R)-(+)-2,8-二甲基-6H,12H-5,11-亚甲基二苯并[b,f][1,5]二吖辛因 (+)-Tröger 碱 |
| MDL Number | MFCD00151116 |
| Beilstein Registry Number | 88612 |
| CAS Number | 21451-74-1 |
| PubChem Substance ID | 24865470 |
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分类
- Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Organic Building Blocks, Polyamines
- {SNA} Analytical Reagents, Analytical/Chromatography, Chiral, Chiral Derivatization Reagents, Chiral LC Derivatization Reagents, Derivatization Reagents, Derivatization Reagents HPLC
相关文献及参考
- 1. J. Org. Chem. 56 , 485, (1991)
- Beil. 23 ,V,9,108
- FT-NMR 1 (2), 665:C / RegBook 1 (1), 1531:I / Structure Index 1 , 239:D:2
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
