Tri-N-Butyltinbromide 三丁基溴化锡

CAS 1461-23-0 MFCD00010660

化学结构图

1461-23-0
SMILES: CCCC[Sn](Br)(CCCC)CCCC

化学属性

Mol. Formula[CH3(CH2)3]3SnBr
Mol. Weight370
Density1.338 g/mL at 25 °C(lit.)
Refractive indexn20/D 1.507(lit.)
Flash Point>110°(230°F)
TSCANo
Boiling Point120-122 °C/2 mmHg(lit.)
Melting Point<0°C

别名和识别编码

Chemical NameTri-N-Butyltinbromide
MDL NumberMFCD00010660
CAS Number1461-23-0
Synonym Tri-n-butyltin bromide tri-n-butyl-tibromide TRI-N-BUTYLBROMOTIN bromotributyl-stannan Tin, tri-n-butyl-, bromide Bromotributyltin TRI-N-BUTYLTIN BROMIDE Tributylstannium bromide tributylstanniumbromide Stannane, tributylbromo- 溴化三正丁錫 三正丁基溴化锡 tributylbromo-stannan TRIBUTYLTIN BROMIDE, TECH., 90% TRIBUTYLTIN BROMIDE Tri-n-butylbromotin 95% BROMOTRIBUTYLTIN Tributylbromotin Tri-n-butyltinbromide,93-95% 三正丁基溴化锡, 93-95% 溴化三正丁锡 Bromotributylstannane; Bromotributyltin; Tributylbromostannane; Tributylstannyl bromide
EC Number215-959-2
PubChem Substance ID305767
Chemical Name Translation三丁基溴化锡
Wiswesser Line NotationE-SN-4&4&4
InChIInChI=1S/3C4H9.BrH.Sn/c3*1-3-4-2;;/h3*1,3-4H2,2H3;1H;/q;;;;+1/p-1
LabNetwork Molecule IDLN02002155
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分类

  • {SNA} Chemical Synthesis, Organometallic Reagents, Organotin, Organotin Halides

相关文献及参考

安全信息

RTECSWH6735000
Packing GroupII
UN Number 1760 UN2788
Risk Statements
  • R26/27/28 Very toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有剧毒
  • R34 Causes burns 会导致灼伤
  • R25 Toxic if swallowed 吞咽有毒
  • R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
  • R21 Harmful in contact with skin 与皮肤接触有害
  • R48/23/25
  • R50/53
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S35 This material and its container must be disposed of in a safe way 该物料及其容器必须以安全方式处置;
Storage condition Moisture Sensitive
GHS Symbol
WGK Germany3
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H330 Fatal if inhaled 吸入致命
  • H310 Fatal in contact with skin 皮肤接触致命
  • H301 Toxic if swallowed 吞食有毒
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P301+P310
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P302+P350
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P301+P310+P330
  • P337+P313
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
  • P302+P352+P312
Signal word Danger
Hazard Codes T+
Hazard Class6.1
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 935 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   SAIGBL Sangyo Igaku.  Japanese Journal of Industrial Health.  (Nippon Sangyo
   Eisei Igakkai, Kosu Eisei Bldg., 1-29-8, Shinjuku, Shinjuku-ku, Tokyo 160,
   Japan)  V.1-    1959-  Volume(issue)/page/year: 15,3,1973

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 100 ug/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J.,
   Prague, Czechoslovakia, Avicenum, 1986  Volume(issue)/page/year: -,1250,1986

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1030 mg/m3/10M
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - lacrimation
   Behavioral - convulsions or effect on seizure threshold
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   NDRC** National Defense Research Committee, Office of Scientific Research
   and Development, Progress Report.  Volume(issue)/page/year:
   NDCrc-132,FEB1942

其他信息

  • Alfa Aesar:Tri-n-butyltin bromide, 95%(1461-23-0)
  • MOL 文件:1461-23-0.mol
  • TSCA:No
  • 三正丁基溴化锡价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/05/25 71185 Tri-n-butyltin bromide, 95% 5g 743元 2010/05/25 71185 Tri-n-butyltin bromide, 95% 25g 2660元 2010/05/25 71185 Tri-n-butyltin bromide, 95% 1g 256元
  • 敏感性:Moisture Sensitive
  • Sigma Aldrich:1461-23-0(sigmaaldrich)

系列性分类


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