(-)-Menthyl Chloroformate (1R)-(-)-薄荷基氯仿
CAS 14602-86-9 MFCD00009694
化学结构图
SMILES: CC(C)[C@@H]1CC[C@@H](C)C[C@H]1OC(=O)Cl |&1:3,6,9|
化学属性
| Mol. Formula | C11H19ClO2 |
|---|---|
| Mol. Weight | 219 |
| Refractive index | n20/D 1.458(lit.) |
| Boiling Point | 108-109 °C/11 mmHg(lit.) |
| Density | 1.02 g/mL at 25 °C(lit.) |
| Flash Point | 70°C(lit.) |
| TSCA | No |
| Vapor Pressure | 0.01 psi ( 20 °C) |
别名和识别编码
| Chemical Name | (-)-Menthyl Chloroformate |
|---|---|
| Synonym | (1R)-(-)-氯甲酸薄荷酯 Chloroformic acid (1R)-menthyl ester (-)-氯甲酸薄荷酯 |
| CAS Number | 14602-86-9 |
| PubChem Substance ID | 87572967 |
| Beilstein Registry Number | 6,36 |
| MDL Number | MFCD00009694 |
| Reaxys-RN | 2414686 |
| Chemical Name Translation | (1R)-(-)-薄荷基氯仿 |
| InChIKey | KIUPCUCGVCGPPA-UHFFFAOYSA-N |
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分类
- {SA} Acid Halides, Analytical Reag
- {SNA} Acid Halides, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Chiral Resolution Reagents, Chiral Resolving Reagents, Derivatization Reagents, Derivatization Reagents HPLC, Organic Building Blocks, UV-VIS, 分析/色谱, 分析试剂
- Acid Halides, Analytical Reagents, Analytical/Chromatography, Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Chiral Resolution Reagents, Chiral Resolving Reagents, Derivatization Reagents, Derivatization Reagents HPLC, Organic Building Blocks,
相关文献及参考
- Chiral derivatizing agent for alcohols and amines, allowing separation by chromatographic or crystallization techniques. For use in the resolution of 1,1'-binaphthyl derivatives, see: J. Org. Chem., 60, 6599 (1995).
- Chiral derivatizing agent for alcohols and amines, allowing separation by chromatographic or crystallization techniques. For use in the resolution of 1,1'-binaphthyl derivatives, see: J. Org. Chem., 60, 6599 (1995).
- Beil. 6 ,IV,155
安全信息
GHS Symbol
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H331 Toxic if inhaled 吸入中毒
- H227 Combustible liquid 可燃液体
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P304+P340+P310
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
- P403+P233
- P305+P351+P338+P310
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P301+P330+P331+P310
- P303+P361+P353
- P284 Wear respiratory protection.? 佩戴呼吸保护装置。
- P370+P378
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
- P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。
- P303+
- R34 Causes burns 会导致灼伤
- R23 Toxic by inhalation 吸入有毒
- R51/53
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S20 When using do not eat or drink 使用时，不得进食，饮水；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S4 Keep away from living quarters 远离生活区；
- S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
