Diethyl Phenyl Orthoformate 原甲酸二乙基苯酯
CAS 14444-77-0 MFCD00009228
化学结构图
SMILES: CCOC(OC1C=CC=CC=1)OCC
化学属性
| Mol. Formula | C11H16O3 |
|---|---|
| Mol. Weight | 196 |
| Density | 1.014 g/mL at 25 °C(lit.) |
| Refractive index | 1.4780 to 1.4820 |
| Boiling Point | 104°C/9.8mmHg |
| Flash Point | 65°C(lit.) |
| TSCA | No |
| Melting Point | -26° |
别名和识别编码
| Chemical Name | Diethyl Phenyl Orthoformate |
|---|---|
| Synonym | Diethoxy-phenoxymethan Orthoameisensäure-diethyl-phenylester Orthoformic acid diethyl phenyl ester Orthoameisensäurediethylphenylester Orthoameisensäurediethyl-phenylester {uni_hamburg} diethyl phenyl orthoformate (diethoxymethoxy)benzene 二乙基苯基甲烷 diethoxymethoxy-benzene Benzene, (diethoxymethoxy)- Diethyl-phenylorthoformiat orthoformic acid diethyl ester-phenyl ester |
| MDL Number | MFCD00009228 |
| Beilstein Registry Number | 1872634 |
| EC Number | 238-421-9 |
| CAS Number | 14444-77-0 |
| PubChem Substance ID | 87574186 |
| Chemical Name Translation | 原甲酸二乙基苯酯 |
| Reaxys-RN | 1872634 |
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分类
- {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; orthoester; 1fragment
- {SNA} Acetals/Ketals/Ortho Esters, Building Blocks, Chemical Synthesis, Organic Building Blocks, Oxygen Compounds
相关文献及参考
- Reacts with Grignard reagents to give aldehyde acetals in good yield: Chem. Ber., 103, 643 (1970). For application to acetylenic Grignards, see: J. Org. Chem., 49, 2031 (1984).
- Short: EINECS
- Short: III/38B
安全信息
GHS Symbol
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P332+P313
- P370+P378
- P305+P351+P338
- P305+P351+P338+P337+P313
- P302+P350
- P337+
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H227 Combustible liquid 可燃液体
- R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
