3,4,5-Trifluorobenzeneboronic Acid 3,4,5-三氟苯硼酸
CAS 143418-49-9 MFCD02093069
化学结构图
SMILES: OB(O)C1=CC(F)=C(F)C(F)=C1
化学属性
| Mol. Formula | C6H4BF3O2 |
|---|---|
| Mol. Weight | 176 |
| Melting Point | 290-295 |
| TSCA | No |
| Density | 1.44 |
别名和识别编码
| Chemical Name | 3,4,5-Trifluorobenzeneboronic Acid |
|---|---|
| CAS Number | 143418-49-9 |
| Alfabeta Name | TRIFLUOROPHENYLBORONICACID 345-,, |
| MDL Number | MFCD02093069 |
| Synonym | 3,4,5-三氟苯硼酸 3,4,5-Trifluorophenylboronic acid 3,4,5-Trifluorobenzeneboronic acid |
| PubChem Substance ID | 24874437 |
| EC Number | 250-023-7 |
| Beilstein Registry Number | 7371914 |
| Chemical Name Translation | 3,4,5-三氟苯硼酸 |
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分类
- Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents, Trisubstituted Aryl Boronic Acids
- {SNA} Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents, Trisubstituted Aryl Boronic Acids
相关文献及参考
- 1. A. Adamczyk-Wozniak, et al., , Quantitative determination of the Lewis acidity of phenylboronic catechol esters - Promising anion receptors for polymer electrolytes Inorg. Chem. Commun. 14 , 1753-1755, (2011)
- 2. N. Gavande, et al., , Identification of Benzopyran-4-one Derivatives (Isoflavones) as Positive Modulators of GABAA Receptors ChemMedChem 6 , 1340-1346, (2011)
- 3. W. Jin, et al., , Regio- and Stereoselective Synthesis of Multisubstituted Olefins and Conjugate Dienes by Using a-Oxo Ketene Dithioacetals as the Building Blocks Org. Lett. 13 , 4272-4275, (2011)
- 4. Z. Zhou, et al., , Suzuki cross-coupling reactions of aryl chlorides using [Cl2Pd(COD)]/piperazine derivative under microwave conditions Appl. Organomet. Chem. 25 , 616-619, (2011)
- 5. N. Liu, et al., , Green synthesis of fluorinated biaryl derivatives via thermoregulated ligand/palladium-catalyzed Suzuki reaction J. Organomet. Chem. 696 , 2641-2647, (2011)
- 6. H. Behniafar and M. Sedaghatdoost, , New fluorinated aromatic poly(ether-amide)s derived from 2,2'-bis(3,4,5-trifluorophenyl)-4,4'-diaminodiphenyl ether and various dicarboxylic acids J. Fluor. Chem. 132 , 276-284, (2011)
- Extremely active catalyst for the reaction of carboxylic acids with primary and secondary amines to give the corresponding amides in very high yields: J. Org. Chem., 61, 4196 (1996).
- Extremely active catalyst for the reaction of carboxylic acids with primary and secondary amines to give the corresponding amides in very high yields: J. Org. Chem., 61, 4196 (1996). Also useful in the one-pot synthesis of acyl azides from carboxylic acids and NaN3: Tetrahedron Lett., 43, 9715 (2002). Mediates the mild, one-pot reduction of carboxylic acids to alcohols with NaBH4: Tetrahedron Lett., 44, 3427 (2003).
- For other boronic acid chemistry, see Appendix 5.
安全信息
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S37 Wear suitable gloves 戴适当手套；
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
- R22 Harmful if swallowed 吞咽有害
- R36 Irritating to eyes 刺激眼睛
- R51/53
GHS Symbol
- P273 Avoid release to the environment. 避免释放到环境中。
- P305+P351+P338
