1,2-Bis[(2S,5S)-2,5-Diethylphospholano]Benzene(1,5-Cyclooctadiene)Rhodium(I) Trifluoromethanesulfonate 1,2-双[(2S,5S)-2,5-二乙基膦烷基]苯(1,5-环辛二烯)三氟甲磺酸铑(I)

CAS 142184-30-3 MFCD00269861

化学结构图

142184-30-3
SMILES: [Rh+].CC[C@H]1CC[C@H](CC)P1C1C=CC=CC=1P1[C@H](CC[C@@H]1CC)CC.[O-]S(=O)(=O)C(F)(F)F.C1CC=CCCC=C1

化学属性

Mol. FormulaC31H48F3O3P2RhS
Mol. Weight722.62
TSCANo
Appearance orange xtl.
Stabilityair sensitive, store cold

别名和识别编码

Chemical Name1,2-Bis[(2S,5S)-2,5-Diethylphospholano]Benzene(1,5-Cyclooctadiene)Rhodium(I) Trifluoromethanesulfonate
Synonym (S,S)-Et-DUPHOS-Rh 1,2-双[(2S,5S)-2,5-二乙基膦烷基]苯(1,5-环辛二烯)三氟甲磺酸铑(I)
MDL NumberMFCD00269861
CAS Number142184-30-3
Chemical Name Translation1,2-双[(2S,5S)-2,5-二乙基膦烷基]苯(1,5-环辛二烯)三氟甲磺酸铑(I)
PubChem Substance ID11146978
InChIInChI=1S/C22H36P2.C8H12.CHF3O3S.Rh/c1-5-17-13-14-18(6-2)23(17)21-11-9-10-12-22(21)24-19(7-3)15-16-20(24)8-4;1-2-4-6-8-7-5-3-1;2-1(3,4)8(5,6)7;/h9-12,17-20H,5-8,13-16H2,1-4H3;1-2,7-8H,3-6H2;(H,5,6,7);/p-1/b;2-1-,8-7-;;/t17-,18-,19-,20-;;;/m0.../s1
LabNetwork Molecule IDLN01368602
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分类

  • {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, DuPhos/BPE, Privileged Ligands and Complexes
  • Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, DuPhos/BPE, Privileged Ligands and Complexes

相关文献及参考

  • 5. Z. Hu and W. Han, , An efficient chiral synthesis of fluoro-containing amino acids: N-benzyloxycarbonyl-2-amino-4,4-difluorobutyric acid methyl ester and its analogs Tetrahedron Lett. 49 , 901-902, (2008)
  • 3. F. Velazquez, et al., , Application of ring-closing metathesis for the synthesis of macrocyclic peptidomimetics as inhibitors of HCV NS3 protease Org. Lett. 9 , 3061-3064, (2007)
  • 4. M. Toumi, et al., , Eight-step total synthesis of the cyclopeptide alkaloid mucronine E Synlett 1 , 29-32, (2008)
  • 1. K. Okuma, et al., , Asymmetric synthesis of (2 S ,3 R )- and (2 S ,3 S )-[2-13C;3-2H] glutamic acid Tetrahedron Lett. 50 , 1482-1484, (2009)
  • 2. K. Oe, et al., , Short and stereoselective synthesis of manzacidins A and C, and their enantiomers Tetrahedron Lett. 49 , 7426-7429, (2008)
  • 6. M. Plesescu, et al., , Synthesis of two labeled forms of proteasome inhibitor MLN273 J. Labelled Comp. Radiopharm. 50 , 428-430, (2007)

安全信息

GHS Symbol
WGK Germany3
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Storage condition Air & Moisture Sensitive
Hazard Codes Xi
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphine Ligands 膦配体
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Organic Phosphates/Phosphites - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. DuPhos/BPE - Privileged Ligands and Complexes
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes
  5. DIPAMP
  1. Functional Group 官能团索引
  2. phosphine
  1. BPE
  2. Rhodium
  1. DUPHOS
  2. Rhodium
  1. BPE
  2. 96-4731 (S,S)-Duphos and BPE Rhodium Catalyst Kit for Asymmetric Hydrogenation
  1. Catalysts
  2. 96-4731 (S,S)-Duphos and BPE Rhodium Catalyst Kit for Asymmetric Hydrogenation
  1. DUPHOS
  2. 96-4731 (S,S)-Duphos and BPE Rhodium Catalyst Kit for Asymmetric Hydrogenation
  1. Catalysts
  2. Rhodium

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