CAS 141-91-3 MFCD00005973-2,6-Dimethylmorpholine 2,6-二甲基吗啉 TAO{mole}

2,6-Dimethylmorpholine 2,6-二甲基吗啉

CAS 141-91-3 MFCD00005973

化学结构图

SMILES: CC1CNCC(C)O1

化学属性

Mol. Formula	C6H13NO
Mol. Weight	115.17
Refractive index	n20/D 1.446(lit.)
Density	0.935 g/mL at 25 °C(lit.)
Boiling Point	147 °C(lit.)
Melting Point	-85 °C(lit.)
Flash Point	48°(120°F)
TSCA	Yes
Solubility	>=0.01 G/100 ML AT 19 ºC

别名和识别编码

Chemical Name	2,6-Dimethylmorpholine
Synonym	AKOS BBS-00004469 Dimethylmorpholine 2,6-Dimethylmorpholine, cis + trans, 97% 2,6-Dimethylmorpholine, mixture of isomers 2,6-DIMETHYLMORPHOLINE, MIXTURE OF ISOME RS 2，6-二甲基吗啡啉 2,6-Dimethyl-2,3,5,6-tetrahydro-4H-1,4-oxazine 2，6-Dimethyl morphaline 2,6-Dimethyl-morpholine 2,6-dimethylmorpholine 2,6-二甲基吗啉 2,6-二甲基吗啉 CIS + TRANS,97% 2,6-Dimethylmorpholine 2,6-Dimethylmorfolin 2,6-Dimethylmorpholine,c&t; Morpholine, 2,6-dimethyl- 2,6-DIMETHYLMORPHOLINE 2,6-dimethyl-morpholin 2,6-DIMETHYLMORPHOLINE, 97%, MIXTURE OF ISOMERS 2,6-dimethyl morpholine 2,6-Dimethylmorpholine(mixture of cis- or trans-) 2，6-Dimethyl-2，3，5，6-thtrahydro-4H-oxazine
MDL Number	MFCD00005973
CAS Number	141-91-3
EC Number	205-509-3
Beilstein Registry Number	103036
PubChem Substance ID	110862
Chemical Name Translation	2,6-二甲基吗啉
Wiswesser Line Notation	T6M DOTJ C1 E1
LabNetwork Molecule ID	LN00007444
InChI	InChI=1S/C6H13NO/c1-5-3-7-4-6(2)8-5/h5-7H,3-4H2,1-2H3

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安全信息

GHS Symbol

WGK Germany1

Hazard statements

H318 Causes serious eye damage 严重伤害眼睛
H311 Toxic in contact with skin 皮肤接触中毒
H226 Flammable liquid and vapour 易燃液体和蒸气
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
H302+H312

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

RTECSQE1750000

Precautionary statements

P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P305+P351+P338
P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P303+P361+P353
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P370+P378

Signal word Danger

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；

Packing GroupIII

UN Number UN 1992 3/PG 3 UN1992 1992

Risk Statements

R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
R21 Harmful in contact with skin 与皮肤接触有害
R10 Flammable 易燃

Hazard Codes Xn

Hazard Class3

Warnings 危化品目录(2015)

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2830 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   UCDS** Union Carbide Data Sheet.  (Union Carbide Corp., 39 Old Ridgebury
   Rd., Danbury, CT 06817)  Volume(issue)/page/year: 11/13/1961

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 710 uL/kg
TOXIC EFFECTS :
   Skin and Appendages - primary irritation (after topical exposure)
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   23,95,1962

TYPE OF TEST            : LC - Lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >4000 ppm/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIHAAP American Industrial Hygiene Association Journal.  (AIHA, 475 Wolf
   Ledges Pkwy., Akron, OH 44311)  V.19-    1958-  Volume(issue)/page/year:
   23,95,1962

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 6666 ug/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 5(Suppl
   1),3,1983

Restrict 危险品

其他信息

Sigma Aldrich:141-91-3(sigmaaldrich)
MOL 文件:141-91-3.mol
图谱信息:2,6-二甲基吗啉(141-91-3)红外图谱(IR1) 2,6-二甲基吗啉(141-91-3)质谱(MS) 2,6-二甲基吗啉(141-91-3)核磁图( 13 CNMR)
方法一:其制备方法是由二-(2-羟基丙基)胺盐酸盐与浓硫酸共热脱水而得，再加碱析出2，6-二甲基吗啉，精馏而得成品。
Alfa Aesar:2,6-二甲基吗啉cis+trans,97% 2,6-Dimethylmorpholine, cis + trans, 97%(141-91-3)
可燃性危险特性:遇明火、高温、氧化剂较易燃; 燃烧产生有毒氮氧化物烟雾
毒性分级:中毒
2,6-二甲基吗啉价格(试剂级):更新日期产品编号产品名称包装价格 2010/05/25 H25954 2,6-二甲基吗啉 cis + trans,97% 2,6-Dimethylmorpholine, cis + trans, 97% 25g 577元 2010/05/25 H25954 2,6-二甲基吗啉 cis + trans,97% 2,6-Dimethylmorpholine, cis + trans, 97% 100g 1428元
类别:易燃液体
MSDS 信息:2,6-二甲基吗啡啉(141-91-3).msds
下游产品:丁苯吗琳 --> 阿莫罗芬
外观性质:无色液体。
急性毒性:口服- 大鼠 LD50: 2830 毫克/ 公斤
灭火剂:干粉、干砂、二氧化碳、泡沫、1211灭火剂
储运特性:库房通风低温干燥; 与氧化剂、酸类分开存放
刺激数据:皮肤- 兔子 10 毫克/ 24小时轻度; 眼睛- 兔子 2 毫克/ 24小时重度
用途一:2，6-二甲基吗啉是杀菌剂丁苯吗啉的中间体。