CAS 14024-64-7 MFCD00013505-Titanium(IV) oxyacetylacetonate 乙酰丙酮氧钛(IV) TAO{mole}

Titanium(IV) oxyacetylacetonate 乙酰丙酮氧钛(IV)

CAS 14024-64-7 MFCD00013505

化学结构图

SMILES: CC(=O)/C=C(/C)\O[Ti](=O)O/C(/C)=C\C(C)=O

化学属性

Mol. Formula	C10H14O5Ti
Mol. Weight	262
TSCA	Yes
Melting Point	200
Solubility	6.6 G/L (20 ºC)

别名和识别编码

Chemical Name	Titanium(IV) oxyacetylacetonate
Synonym	Bis(2,4-pentanedionato)titanium oxide Bis(acetylacetonato)oxotitanium(IV) Bis(acetylacetonato)oxotitanium(IV)Titanyl acetylacetonate TiO(acac)2 TiO(acac)2 乙酰丙酮氧化钛(IV) TiO(acac)2, Titanium(IV) oxideacetylacetonate Titanium acetonyl acetonate Titanium oxide bis(acetylacetonate) Titanium(IV)oxide acetylacetonate Titanium, oxobis(2,4-pentanedionato-O,O') Titanyl bis(acetylacetonate) 乙酰丙酮氧化钛(IV) 乙酰丙酮氧钛(IV)
MDL Number	MFCD00013505
PubChem Substance ID	87576231
CAS Number	14024-64-7
EC Number	237-861-9
Chemical Name Translation	乙酰丙酮氧钛(IV)
Wiswesser Line Notation	1V1V1 2 &-TI-

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安全信息

WGK Germany3

GHS Symbol

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P302+P352+P312+P362+P364
P304+P340+P312
P305+P351+P338
P305+P351+P338+
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P332+P313
P501 Dispose of contents/container to..… 处理内容物/容器.....

Hazard statements

H332 Harmful if inhaled 吸入有害
H315 Causes skin irritation 会刺激皮肤
H302 Harmful if swallowed 吞食有害
H312 Harmful in contact with skin 皮肤接触有害
H335 May cause respiratory irritation 可能导致呼吸道刺激
H351 Suspected of causing cancer 怀疑致癌
H319 Causes serious eye irritation 严重刺激眼睛
H302+H312+H332

Hazard Codes Xn

RTECSXR2330000

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves

Signal word Warning

Safety Statements

S22 Do not breathe dust 不要吸入粉尘；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
S7 Keep container tightly closed 保存在严格密闭容器中；

Risk Statements

R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
R22 Harmful if swallowed 吞咽有害
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intramuscular
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 360 mg/kg/69W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Blood - lymphoma, including Hodgkin's disease
   Tumorigenic - tumors at site of application
REFERENCE :
   NCIUS* Progress Report for Contract No. PH-43-64-886, Submitted to the
   National Cancer Institute by The Institute of Chemical Biology, University
   of San Francisco.  (San Francisco, CA 94117)  Volume(issue)/page/year:
   PH43-64-886

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Intramuscular
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2025 mg/kg/34W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Tumorigenic - tumors at site of application
REFERENCE :
   NCIUS* Progress Report for Contract No. PH-43-64-886, Submitted to the
   National Cancer Institute by The Institute of Chemical Biology, University
   of San Francisco.  (San Francisco, CA 94117)  Volume(issue)/page/year:
   PH43-64-886

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 650 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NCIUS* Progress Report for Contract No. PH-43-64-886, Submitted to the
   National Cancer Institute by The Institute of Chemical Biology, University
   of San Francisco.  (San Francisco, CA 94117)  Volume(issue)/page/year:
   PH43-64-886