2,3,4,6-Tetra-O-Acetyl-β-D-Galactopyranosyl Azide 2,3,4,6-四-O-乙酰基-β-D-叠氮化吡喃葡萄糖
CAS 13992-25-1 MFCD00181721
化学结构图
SMILES: CC(=O)O[C@H]1[C@@H](COC(C)=O)O[C@@H](N=[N+]=[N-])[C@H](OC(C)=O)[C@H]1OC(C)=O
化学属性
| Mol. Formula | C14H19N3O9 |
|---|---|
| Mol. Weight | 373.32 |
| Melting Point | 127-131 °C(lit.) |
| Density | 1.422 |
别名和识别编码
| Chemical Name | 2,3,4,6-Tetra-O-Acetyl-β-D-Galactopyranosyl Azide |
|---|---|
| MDL Number | MFCD00181721 |
| PubChem Substance ID | 24873728 |
| CAS Number | 13992-26-2 |
| Synonym | 1-叠氮-1-脱氧-β-D-吡喃半乳糖苷四乙酸酯 NSC 272456 1-叠氮-1-脱氧-β-D-吡喃葡萄糖苷四乙酸酯 |
| EC Number | 250-023-7 |
| Beilstein Registry Number | 2384789 |
| Chemical Name Translation | 2,3,4,6-四-O-乙酰基-β-D-叠氮化吡喃葡萄糖 |
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分类
- {SNA} Aliphatic Azides, Azides,
- {SA} Aliphatic Azides, Azides, Building Blocks, Carbohydrate Azides, Carbohydrate Chemistry, Carbohydrate Derivatives, Chemical Biology, Chemical Synthesis, Conjugation Chemistry: Azides, Alkynes and Other Reagents, Nitrogen Compounds, Organic Building Blocks
- Aliphatic Azides,
- {SNA} Aliphatic Azides, Azides, Building Blocks, Carbohydrate Azides, Carbohydrate Chemistry, Carbohydrate Derivatives, Chemical Biology, Chemical Synthesis, Conjugation Chemistry: Azides, Alkynes and Other Reagents, Copper Click Chemistry, Nitrogen Compounds, Organic Building Blocks
相关文献及参考
- 5. Nuti, F.; et al., Posttranslationally modified peptides efficiently mimicking neoantigens: a challenge for theragnostics of autoimmune diseases Biopolymers 94 , 791-799, (2010)
- 2. Salmon, A. J.; et al., Synthesis of glycoconjugate carbonic anhydrase inhibitors by ruthenium-catalyzed azide-alkyne 1,3-dipolar cycloaddition Bioorg. Med. Chem. Lett. 21 , 6058-6061, (2011)
- 3. Kun, S.; et al., Synthesis of variously coupled conjugates of D-glucose, 1,3,4-oxadiazole, and 1,2,3-triazole for inhibition of glycogen phosphorylase Carbohydr. Res. 346 , 1427-1438, (2011)
- 1. Luo, L.; et al., Synthesis of (Glycopyranosyl-triazolyl)-purines and Their Inhibitory Activities against Protein Tyrosine Phosphatase 1B (PTP1B) Chem. Biodivers. 8 , 2035-2044, (2011)
- 4. Hemantha, H. P.; Sureshbabu, V. V., Poly(vinyl)chloride supported palladium nanoparticles: catalyst for rapid hydrogenation reactions Org. Biomolecular Chem. 9 , 2597-2601, (2011)
安全信息
GHS Symbol
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
