Potassium Hexacyanocobaltate(Iii) 六氰基钴(III)酸钾

CAS 13963-58-1 MFCD00011391

化学结构图

13963-58-1
SMILES: [K+].[K+].[K+].N#C[Co-3](C#N)(C#N)(C#N)(C#N)C#N

化学属性

Mol. FormulaC6CoK3N6
Mol. Weight332
Density1.878
Melting Pointdec.
SolubilitySoluble in water and acetic acid solutions. Insoluble in alcohol
TSCAYes
Appearance 钴氰化钾(13963-58-1)为淡黄色结晶，溶于水。

别名和识别编码

Chemical NamePotassium Hexacyanocobaltate(Iii)
Synonym Tripotassium hexacyanocobaltate(3-) Kaliumhexacyanocobaltat(III) Cobaltate(3-), hexakis(cyano-C)-, tripotassium, (OC-6-11)- Cobaltate(3-), hexakis(cyano-kappaC)-, tripotassium, (OC-6-11)- Potassium hexacyanocobaltate(3-) Potassium cobaltic cyanide 钴氰化钾 Potassium cobalticyanine Potassium hexacyanocobaltate (III) Tri-potassium hexacyanocobaltate(III) Tripotassium hexacyanocobaltate Cobaltate(3-), hexakis(cyano-κC)-, tripotassium, (OC-6-11)- Cobaltate(3-), hexacyano-, tripotassium Potassium cobalt cyanide Potassium hexacyanocobaltate (K3Co(CN)6) Potassium cobalticyanide Potassium hexacyanocobaltate(III) Kaliumhexacyanokobalt(III) Potassium cyanocobaltate(III) (K3[Co(CN)6]) Cobaltate(3-), hexakis[cyano-C]-, (OC-6-11)-, tripotassium, (OC-6-11)- Tripotassium hexacyanocobaltate(III) Cobalt potassium cyanide (CoK3(CN)6)
MDL NumberMFCD00011391
PubChem Substance ID24853076
EC Number237-742-1
CAS Number13963-58-1
Merck Number14,7637
Chemical Name Translation六氰基钴(III)酸钾
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分类

  • {uni_hamburg} no charge; metal-organic; 4fragments; ionic
  • {SNA} Analytical Reagents, Analytical Reagents for General Use, Analytical/Chromatography, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cobalt, Puriss

相关文献及参考

  • Short: III/20a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cl Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20a Year: 1988 Keyword: NQR ISBN: 3-540-18161-X ISBN: 978-3-540-18161-3 Internet Resource: DOI:10.1007/b31153 RefComment: IX,677 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: III/20b Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei Cl ... Rb Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/20b Year: 1988 Keyword: NQR ISBN: 3-540-18483-X ISBN: 978-3-540-18483-6 Internet Resource: DOI:10.1007/b86664 RefComment: IX,717 pages. Hardcover Abstract: Nuclear Quadrupole Resonance Spectroscopy has become a standard method for structural research in molecular and solid state physics as well as for different branches of chemistry. The volumes cover data for more than 8,000 substances in the solid state. Data for free molecules have been published in volumes II/14 and II/15 of the New Series. The tables are arranged according to the atomic number of the elements.
  • Short: III/31a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cu Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/31a Year: 1993 Keyword: NQR ISBN: 3-540-55146-8 ISBN: 978-3-540-55146-1 Internet Resource: DOI:10.1007/b43999 RefComment: VIII, 437 pages. Hardcover Abstract: Volume III/31 contin

安全信息

WGK Germany3
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
Signal word Danger
Hazard statements
  • H331 Toxic if inhaled 吸入中毒
  • H311 Toxic in contact with skin 皮肤接触中毒
  • H301 Toxic if swallowed 吞食有毒
RTECSGF9470000
GHS Symbol
Personal Protective Equipment Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S7/9 Keep container tightly closed and in a well-ventilated place 保持容器严格密闭，置于通风良好的场所；
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
  • R32 Contact with acids liberates very toxic gas 与酸接触释放出毒性很高的气体
  • R33 Danger of cumulative effects 有累积作用的危险
Hazard Codes 6.1 T
UN Number 1588
Packing GroupII
Hazard Class6.1(b) 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 1529 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPMSAE Journal of Pharmaceutical Sciences.  (American Pharmaceutical Assoc.,
   2215 Constitution Ave., NW, Washington, DC 20037)  V.50-    1961-
   Volume(issue)/page/year: 52,59,1963

其他信息

  • Sigma Aldrich:13963-58-1(sigmaaldrich)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Cobalt Catalysis 钴催化剂
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Cobalt Catalysis 钴催化剂
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Chromium
  1. Analytical & Chromatography 分析化学与色谱
  2. Adsorbents, Filter Aids and Drying Agents
  3. Other Drying Agents

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