(R,R)-(-)-N,N-Bis(3,5-DI-Tert-Butylsalicylidene)-1,2-Cyclohexanediamine (R,R)-(-)-N,N’-双(3,5-二叔丁基邻羟亚苄基)-1,2-环己二胺

CAS 135616-40-9 MFCD00191800

化学结构图

135616-40-9
SMILES: CC(C)(C)C1=CC(=C(O)C(/C=N/[C@@H]2CCCC[C@H]2/N=C/C2C=C(C=C(C=2O)C(C)(C)C)C(C)(C)C)=C1)C(C)(C)C

化学属性

Mol. FormulaC36H54N2O2
Mol. Weight546.84
Melting Point206.0 to 210.0 deg-C
Appearance yellow pwdr.

别名和识别编码

Chemical Name(R,R)-(-)-N,N-Bis(3,5-DI-Tert-Butylsalicylidene)-1,2-Cyclohexanediamine
Synonym (R,R)-Jacobsen 配体 (R,R)-(-)-N,N′-双(3,5-二-叔丁基亚水杨基)-1,2-环己二胺
Beilstein Registry Number5464823
PubChem Substance ID253662530
CAS Number135616-40-9
MDL NumberMFCD00191800
Chemical Name Translation(R,R)-(-)-N,N’-双(3,5-二叔丁基邻羟亚苄基)-1,2-环己二胺
Reaxys-RN6832745
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分类

  • {SA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, SALENs
  • Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, SALENs

相关文献及参考

  • 1. M.J.E.C. Van der Maarel et al, Properties and applications of starch-converting enzymes of the α-amylase family J. Biotechnol. 94 , 137-155, (2002) 摘要
  • 2. S. Sivaramakrishnan et al, α-amylases from microbial sources- an overview on recent developments Food Technol. 44 , 173-154, (2006)
  • J. Am. Chem. Soc. 113 , 7063, (1991)
  • Jacobsen, E.N. et al. J. Am. Chem. Soc. 113 , 7063, (1991)
  • Deng, L. Jacobsen, E.N. J. Org. Chem. 57 , 4320, (1992)
  • Chang, S. et al. J. Org. Chem. 58 , 6939, (1993)
  • FT-IR 2 (3), 4056:B / Structure Index 1 , 429:B:5

安全信息

Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
WGK Germany3
GHS Symbol
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类

  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Analytical Reagents for General Use - Analytical Reagents
  4. Puriss p.a. - Analytical Reagents for General Use
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. SALENs - Privileged Ligands and Complexes
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Privileged Ligands and Complexes - Chiral Catalysts, Ligands, and Reagents
  5. SALENs - Privileged Ligands and Complexes
  1. Jacobsen Ligand
  2. Nitrogen
  1. Ligands
  2. Nitrogen

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