(S,S)-(+)-N,N-Bis(3,5-DI-Tert-Butylsalicylidene)-1,2-Cyclohexanediamine (S,S)-(+)-N,N’-双(3,5-二叔丁基邻羟亚苄基)-1,2-环己二胺
CAS 135616-36-3 MFCD00191801
化学结构图
SMILES: CC(C)(C)C1=CC(=C(O)C(/C=N/[C@H]2CCCC[C@@H]2/N=C/C2C=C(C=C(C=2O)C(C)(C)C)C(C)(C)C)=C1)C(C)(C)C
化学属性
| Mol. Formula | [[(CH3)3C]2C6H2-2-(OH)CH=N]2C6H10 |
|---|---|
| Mol. Weight | 546.83 |
| Melting Point | 203-206 °C(lit.) |
| Appearance | yellow pwdr. |
别名和识别编码
| Chemical Name | (S,S)-(+)-N,N-Bis(3,5-DI-Tert-Butylsalicylidene)-1,2-Cyclohexanediamine |
|---|---|
| Synonym | (S,S)-(+)-N,N′-双(3,5-二-叔丁基亚水杨基)-1,2-环己二胺 (S,S)-Jacobsen 配体 |
| Beilstein Registry Number | 5464823 |
| PubChem Substance ID | 24865245 |
| CAS Number | 135616-36-3 |
| MDL Number | MFCD00191801 |
| Chemical Name Translation | (S,S)-(+)-N,N’-双(3,5-二叔丁基邻羟亚苄基)-1,2-环己二胺 |
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分类
- {SA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, SALENs
- Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes, SALENs
相关文献及参考
- 1. Jacobsen, E.N. et al. J. Am. Chem. Soc. 113 , 7063, (1991)
- 2. Deng, L. Jacobsen, E.N. J. Org. Chem. 57 , 4320, (1992)
- 3. Chang, S. et al. J. Am. Chem. Soc. 58 , 6939, (1993)
- FT-IR 2 (3), 4056:C / Structure Index 1 , 429:C:5
安全信息
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
GHS Symbol
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
