Iron(0) pentacarbonyl
CAS 13463-40-6 MFCD00011001
化学结构图
SMILES: [Fe].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]
化学属性
| Mol. Formula | C5FeO5 |
|---|---|
| Mol. Weight | 195.90 |
| Density | 1.49 g/mL at 25 °C(lit.) |
| Refractive index | n20/D 1.5196(lit.) |
| Flash Point | -15°(5°F) |
| Solubility | Soluble in nickel tetracarbonyl and organic solvents. Insoluble in water |
| TSCA | Yes |
| Boiling Point | 103 °C(lit.) |
| Melting Point | -20 °C(lit.) |
| Autoignition Point | 122 °F |
| Vapor Density | 6.74 (vs air) |
| Vapor Pressure | 35 mmHg ( 25 °C) |
| Appearance | orange liq. |
| Stability | air sensitive, store cold |
别名和识别编码
| Chemical Name | Iron(0) pentacarbonyl |
|---|---|
| MDL Number | MFCD00011001 |
| Synonym | Iron pentacarbonyl (Fe(CO)5) ironpentacarbonyl 羰基铁 Pentacarbonyliron Eisenpentacarbonyl R 20 Iron, pentacarbonyl- pentacarbonyliron Pentacarbonyleisen Pentacarbonyliron(0) Iron pentacarbonyl Fe (CO)5 FER pentacarbonyle pentacarbonyl iron Iron carbonyl (Fe(CO)5), (TB-5-11)- Iron pentacarbonyl (liquid) 五羰基铁 |
| EC Number | 236-670-8 |
| CAS Number | 13463-40-6 |
| Merck Number | 14,5099 |
| PubChem Substance ID | 24851709 |
| Wiswesser Line Notation | FE C-O*4 |
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分类
- {uni_hamburg} no charge; metal-organic; metal carbonyl; 1fragment
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Iron
相关文献及参考
- 1. Chen, L.-G.; et al., Addition reaction of Fe(CO)n (n = 3~5) on fullerene C50, C60, and C70: A density functional theory study Chin. J. Structural Chem. 30 , 1161, (2011)
- 2. Amarasinghe, D. S.; et al., Effect of CO Pressure Gradients on the Photochemistry and Thermal Chemistry of Fe(CO)5 Physisorbed into Porous Vycor Glass J. Phys. Chem. C 115 , 20824, (2011)
- 3. Snovski, R.; et al., Novel magnetic Fe onion-like fullerene micrometer-sized particles of narrow size distribution J. Magn. Magn. Mater. 324 , 90, (2011)
- 4. Tsutsumi, H.; et al., New catalyst systems for iron-catalyzed hydrosilane reduction of carboxamides Chem. Commun. 47 , 6581, (2011)
- 5. Yamada, Y.; et al., Photocatalytic Hydrogen Evolution under Highly Basic Conditions by Using Ru Nanoparticles and 2-Phenyl-4-(1-naphthyl)quinolinium Ion J. Am. Chem. Soc. 133 , 16136, (2011)
- Merck 14 ,5099
- Fieser 1 ,519 / Fieser 2 ,229 / Fieser 3 ,167 / Fieser 4 ,268 / Fieser 5 ,357 / Fieser 6 ,304 / Fieser 10 ,221 / Fieser 13 ,152 / Fieser 17 ,270
- Aldrich MSDS 1 , 1107:D / Corp MSDS 1 (1), 2014:C / FT-IR 1 (2), 1298:A / FT-IR 2 (3), 4591:D / IR-Spectra (3), 1566:B / RegBook 1 (2), 3141:I / Sax 6 , 1626 / Vapor Phase 3 , 1690:C
- Short: II/2 Title: Magnetic Properties of Coordination and Organometallic Transition Metal Compounds Author: König, E. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: II/2 Year: 1966 ISBN: 3-540-03593-1 ISBN: 978-3-540-03593-0 Internet Resource: DOI:10.1007/b19948 RefComment: 170 figs., XII, 578 pages. Hardcover Abstract: The data compiled refer to susceptibility measurements (susceptibility, Curie-constants, magnetic moments, transition temperatures) and ESR-measurements (g-factors and other param
安全信息
- R11 Highly flammable 非常易燃
- R24 Toxic in contact with skin 与皮肤接触有毒
- R26/28 Very toxic by inhalation and if swallowed 吸入及吞食都有剧毒
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
GHS Symbol
- H300+H330
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H311 Toxic in contact with skin 皮肤接触中毒
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P301+P310
- P284 Wear respiratory protection.? 佩戴呼吸保护装置。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intravenous SPECIES OBSERVED : Rodent - rabbit DOSE/DURATION : 11 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA) V.18-31, 1936-49. For publisher information, see AEHLAU. Volume(issue)/page/year: 25,415,1943
TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 910 mg/m3/30M TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : AMIHAB AMA Archives of Industrial Health. (Chicago, IL) V.11-21, 1955-60. For publisher information, see AEHLAU. Volume(issue)/page/year: 19
T
TYPE OF TEST : LCLo - Lowest published lethal concentration ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rabbit DOSE/DURATION : 250 ppm/45M TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : 34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969 Volume(issue)/page/year: -,335,1969
TYPE OF TEST : LC50 - Lethal concentration, 50 percent kill ROUTE OF EXPOSURE : Inhalation SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 910 mg/m3/30M TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : AMIHAB AMA Archives of Industrial Health. (Chicago, IL) V.11-21, 1955-60. For publisher information, see AEHLAU. Volume(issue)/page/year: 19,11,1959
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROU
TYPE OF TEST : LD50 - Lethal dose, 5
