Dichloro-R-2,2’-Bis(Diphenylphosphino)-1,1’-Binaphthyl Ruthenium 二氯-R-2,2’-双(二苯基膦)-1,1’-联萘钌
CAS 134524-84-8 MFCD34524848
化学结构图
SMILES: Cl[Ru]Cl.c1ccc(P(c2ccccc2)c2ccc3ccccc3c2-c2c(P(c3ccccc3)c3ccccc3)ccc3ccccc23)cc1
化学属性
| Mol. Weight | 794.66 |
|---|---|
| Mol. Formula | C44H32Cl2P2Ru |
| Melting Point | >;300 °C |
| Appearance | orange pwdr. |
| Stability | air sensitive |
别名和识别编码
| Synonym | (S)-[2,2′-双(二苯基膦)-1,1′-联萘]二氯化钌 (S)-BINAP 二氯化钌络合物 (S)-[1,1′-联萘]-2,2′-二基双[二苯膦]钌络合物 [(1S)-[1,1′-Binaphthalene]-2,2′-diylbis[diphenylphosphine-κP]]dichloro-ruthenium (S)-[1,1′-联萘]-2,2′-二基双[二苯膦]钌络合物 (S)-BINAP 二氯化钌络合物 [(1S)-[1,1′-Binaphthalene]-2,2′-diylbis[diphenylphosphine-κP]]dichloro-ruthenium |
|---|---|
| Chemical Name | Dichloro-R-2,2’-Bis(Diphenylphosphino)-1,1’-Binaphthyl Ruthenium |
| Chemical Name Translation | 二氯-R-2,2’-双(二苯基膦)-1,1’-联萘钌 |
| MDL Number | MFCD01073794 |
| PubChem Substance ID | 11136527 |
| CAS Number | 134524-84-8 |
| Reaxys-RN | 15397757 |
| InChI | InChI=1S/C44H32P2.2ClH.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;;;/h1-32H;2*1H;/q;;;+2/p-2 |
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分类
- {SNA} Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Hydrogenation
安全信息
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
