Heptyltriphenylphosphonium bromide, 98% (1-庚基)三苯基溴化鏻
CAS 13423-48-8 MFCD00050249
化学结构图
SMILES: CCCCCCC[P+](c1ccccc1)(c1ccccc1)c1ccccc1.[Br-]
化学属性
| Mol. Formula | C25H30BrP |
|---|---|
| Mol. Weight | 441 |
| Melting Point | 173-176 |
| TSCA | No |
| Boiling Point | 173-176 |
别名和识别编码
| Chemical Name | Heptyltriphenylphosphonium bromide, 98% |
|---|---|
| MDL Number | MFCD00050249 |
| PubChem Substance ID | 87570932 |
| CAS Number | 13423-48-8 |
| EC Number | 236-539-5 |
| Reaxys-RN | 3580843 |
| Beilstein Registry Number | 3580843 |
| Synonym | Triphenylheptylphosphonium bromide; n-Heptyltriphenylphosphonium bromide; Bromo(heptyl)triphenylphosphorane 正庚基三苯基溴化磷 |
| Chemical Name Translation | (1-庚基)三苯基溴化鏻 |
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分类
- {SNA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents
相关文献及参考
- 1. R. Hrdina, et al., J. Am. Chem. Soc. 133 , 7624-7627, (2011)
- 2. J. Ghostin, et al., Nat. Prod. Res. 25 , 560-568, (2011)
- 3. W. Peng, et al., Tetrahedron 66 , 9714-9720, (2010)
- 4. D. Fiorini, et al., Synthesis 9 , 1550-1556, (2010)
- 5. X. Lu, et al., J. Org. Chem. 74 , 3192-3195, (2009)
- 6. J. Chen, et al., Bioorg. Med. Chem. Lett. 16 , 5805-5808, (2006)
- FT-IR 2 (2), 3329:A / RegBook 1 (2), 2273:D / Structure Index 1 , 355:D:8
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
