Chlorotripyrrolidinophosphonium hexafluorophosphate 氯代三吡咯烷基鏻六氟磷酸盐

CAS 133894-48-1 MFCD00210035

化学结构图

133894-48-1
SMILES: F[P-](F)(F)(F)(F)F.Cl[P+](N1CCCC1)(N1CCCC1)N1CCCC1

化学属性

Mol. FormulaC12H24ClF6N3P2
Mol. Weight422
Melting Point145°
TSCANo
Boiling Point145-148

别名和识别编码

Chemical NameChlorotripyrrolidinophosphonium hexafluorophosphate
Synonym Pyclop
Beilstein Registry Number6842341
PubChem Substance ID172089143
CAS Number133894-48-1
MDL NumberMFCD00210035
Chemical Name Translation氯代三吡咯烷基鏻六氟磷酸盐
Reaxys-RN6842341
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分类

  • {SNA} Chemical Biology, Chemical Synthesis, Coupling, Peptide Chemistry, Peptide Coupling, Phosphonium/Uronium/Formamidinium, Synthetic Reagents

相关文献及参考

  • 1. Johan Svenson, et al Biochemistry 47 , 3777-3788, (2008) 摘要
  • 2. Chanaz Salmi, et al Lett. Org. Chem. 2 , 628-633, (2005)
  • 3. Frank Hoffmann, et al Phosphorus, Sulfur Silicon Relat. Elem. 178 , 299-309, (2003)
  • 4. Mark Wehner, et al Eur. J. Org. Chem. 1 , 138-153, (2005)
  • 5. Natsuhisa Oka, et al Tetrahedron 62 , 3667-3673, (2006)
  • 6. P. Rzepecki, et al J. Org. Chem. 69 , 5168-5178, (2004)
  • J. Coste et al. J. Org. Chem. 59 , 2437, (1994)

安全信息

Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331+P310
  • P303+P361+P353+P310+P363
  • P304+P340+P310
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
WGK Germany3
GHS Symbol
Signal word Danger
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Hazard Codes 8 C
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
UN Number 1759
Risk Statements
  • R34 Causes burns 会导致灼伤
Storage condition Moisture Sensitive 0-10°C
Packing GroupII
Hazard Class8

系列性分类


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