Ethyl 2-Oxo-3-(Triphenylphosphoranylidene)Propanoate 2-氧代-3-(三苯基膦亚基)丙酸乙酯

CAS 13321-61-4 MFCD00208428

化学结构图

13321-61-4
SMILES: CCOC(=O)C(=O)C=P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1

化学属性

Mol. Formula(C6H5)3P=CHCOCO2C2H5
Mol. Weight376.38
Melting Point175 °C (dec.)(lit.)

别名和识别编码

Chemical NameEthyl 2-Oxo-3-(Triphenylphosphoranylidene)Propanoate
Synonym 2-Ethoxycarbonyl-2-oxoethylidenetriphenylphosphorane NSC 647346 2-Ethoxycarbonyl-2-oxoethylidenetriphenylphosphorane NSC 647346 [(Carboxycarbonyl)methylene]triphenylphosphorane ethyl ester [(Carboxycarbonyl)methylene]triphenylphosphorane ethyl ester (三苯基膦)丙酮酸乙酯
MDL NumberMFCD00208428
PubChem Substance ID24873999
CAS Number13321-61-4
Chemical Name Translation2-氧代-3-(三苯基膦亚基)丙酸乙酯
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分类

  • {SNA} C-C Bond Formation, Chemical Synthesis, Olefination, Synthetic Reagents, Wittig Reagents

相关文献及参考

  • 1. G. Cremonesi, et al., Heterocycles 74 , 1015-1018, (2007)
  • 2. H. Chiu and R. P. Cheng, Org. Lett. 9 , 5517-5520, (2007)
  • 3. F. Palacios, et al., Eur. J. Org. Chem. 12 , 2843-2850, (2006)
  • 4. Y. Choe, et al., Bioorg. Med. Chem. 13 , 2141-2156, (2005)
  • 5. S. Olgen and C. K. Chu, Z. Naturforsch. B 56 , 804-811, (2001)
  • 6. S. Velaquez, et al., Antiviral Chem. Chemother. 9 , 481-489, (1998)

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter

系列性分类


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