N-(Benzyloxycarbonyloxy)succinimide N-苄基琥珀酰亚胺碳酸酯

CAS 13139-17-8 MFCD00005513

化学结构图

13139-17-8
SMILES: O=C(OCc1ccccc1)ON1C(=O)CCC1=O

化学属性

Mol. FormulaC12H11NO5
Mol. Weight249.22
Melting Point80-82°C
Density1.38
TSCANo
Boiling Point392.32 °C at 760 mmHg

别名和识别编码

Chemical NameN-(Benzyloxycarbonyloxy)succinimide
Synonym N-(Benzyloxycarbonyloxy)succinimide {LY} N-(Benzyloxycarbonyloxy)succinimide {} {LY} N-(Benzyloxycarbonyloxy)succinimide {} {} {LY} N-(Benzyloxycarbonyloxy)succinimide {} {} {} {LY} N-(Benzyloxycarbonyloxy)succinimide {} {} {} {} {LY} N-(Benzyloxycarbonyloxy)succinimide {} {} {} {} {} {LY} N-(Benzyloxycarbonyloxy)succinimide {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-(Benzyloxycarbonyloxy)succinimide {} {} {} {} {} {} {} {LY} N-(Benzyloxycarbonyloxy)succinimide {} {} {} {} {} {} {} {} {LY} N-(Benzyloxycarbonyloxy)succinimide {} {} {} {} {} {} {} {} {} {LY} N-(Benzyloxycarbonyloxy)succinimide {} {} {} {} {} {} {} {} {} {} {LY} N-(Benzyloxycarbonyloxy)succinimide {} {} {} {} {} {} {} {} {} {} {} {LY} N-(Benzyloxycarbonyloxy)succinimide {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-(Benzyloxycarbonyloxy)succinimide {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-(Benzyloxycarbonyloxy)succinimide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N-(Benzyloxycarbonyloxy)succi
MDL NumberMFCD00005513
Beilstein Registry Number1387927
CAS Number13139-17-8
EC Number236-075-3
PubChem Substance ID87566154
Reaxys-RN1387927
Chemical Name TranslationN-(苄氧羰基氧基)琥珀酰亚胺
LabNetwork Molecule IDLN00213937
InChIKeyMJSHDCCLFGOEIK-UHFFFAOYSA-N
Canonical SMILESO=C(OCC1=CC=CC=C1)ON2C(CCC2=O)=O
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分类

  • {SNA} Amine Protection, Chemical Biology, Chemical Synthesis, Others, Peptide Chemistry, Protecting and Derivatizing Reagents, Protection and Derivatization, Synthetic Reagents
  • Amine Protection, Chemical Biology, Chemical Synthesis, Others, Peptide Chemistry, Protecting and Derivatizing Reagents, Protection and Derivatization, Synthetic Reagents
  • {SNA} Amine Protection, Chemical Biology, Chemical Synthesis, Other Protecting and Derivatizing Reagents, Peptide Chemistry, Protecting and Derivatizing Reagents, Protection and Derivatization, Synthetic Reagents

相关文献及参考

  • Especially convenient for the selective protection of the -amino group of lysine and ornithine: Can. J. Chem., 54, 733 (1976); Rec. Trav. Chim., 99, 400 (1980). See Appendix 6.
  • Selective reagent for the introduction of the benzyloxycarbonyl (Cbz or Z) protecting group, avoiding the formation of amino acid dimers: Tetrahedron Lett., 4765 (1966); J. Antibiot., 25, 695 (1972); 34, 513 (1981); Can. J. Chem., 60, 976 (1982).

安全信息

Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
WGK Germany3
Signal word Warning
GHS Symbol
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Risk Statements
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Storage condition -20°C {LY} -20°C 0-10 0-10°C Moisture Sensitive {} {LY} -20°C {} {} {LY} -20°C {} {} {} {LY} -20°C {} {} {} {} {LY} -20°C {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Hazard Codes Xi

其他信息

  • 不溶于水。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Chemical Biology 生物化学
  3. Peptide Chemistry 多肽化学
  4. Amine Protection - Peptide Chemistry
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Amides - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Protection and Derivatization - Synthetic Reagents
  4. Protecting and Derivatizing Reagents - Protection and Derivatization
  5. Others - Protecting and Derivatizing Reagents
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Condensation & Active Esterification
  1. Functional Group 官能团索引
  2. carbonic acid monoester
  1. Life Science 生命科学
  2. Biochemistry / Glyco-Chemistry
  3. Peptide Synthesis

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