tert-Butyl N-succinimidyl carbonate N-琥珀酰亚胺碳酸叔丁酯

CAS 13139-12-3 MFCD00037903

化学结构图

13139-12-3
SMILES: CC(C)(C)OC(=O)ON1C(=O)CCC1=O

化学属性

Mol. FormulaC9H13NO5
Mol. Weight215
Melting Point95
TSCAYes

别名和识别编码

Chemical Nametert-Butyl N-succinimidyl carbonate
Synonym Boc-OSu N-琥珀酰亚胺碳酸叔丁酯 叔丁氧羰酰丁二酰亚胺
MDL NumberMFCD00037903
PubChem Substance ID57647838
Beilstein Registry Number1536756
CAS Number13139-12-3
EC Number236-071-1
Chemical Name TranslationN-琥珀酰亚胺碳酸叔丁酯
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分类

  • {SNA} Amine Protection, Chemical Biology, Chemical Synthesis, Others, Peptide Chemistry, Protecting and Derivatizing Reagents, Protection and Derivatization, Synthetic Reagents
  • {SNA} Amine Protection, Chemical Biology, Chemical Synthesis, Other Protecting and Derivatizing Reagents, Peptide Chemistry, Protecting and Derivatizing Reagents, Protection and Derivatization, Synthetic Reagents
  • Amine Protection, Chemical Biology, Chemical Synthesis, Others, Peptide Chemistry, Protecting and Derivatizing Reagents, Protection and Derivatization, Synthetic Reagents

相关文献及参考

  • 1. M. Franke et al. Tetrahedron Lett. , 4765, (1966)
  • 2. H. Gross, L. Bilk Justus Liebigs Ann. Chem. 725 , 212, (1969)
  • 3. J. Hora Biochim. Biophys. Acta 310 , 264, (1973) 摘要

安全信息

WGK Germany2
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P310
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P405 Store locked up. 上锁保管。
  • P501a
Hazard statements
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H302 Harmful if swallowed 吞食有害
Hazard Codes Xn
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Signal word Warning
Safety Statements
  • S1/2 None 上锁保管并避免儿童触及；
  • S22 Do not breathe dust 不要吸入粉尘；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S51 Use only in well-ventilated areas 仅在通风良好的场所使用；
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R25 Toxic if swallowed 吞咽有毒
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R42 May cause sensitisation by inhalation 吸入会产生过敏反应
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
Storage condition Moisture Sensitive

系列性分类

  1. Life Science 生命科学
  2. Biochemicals and Reagents 生化试剂
  3. Peptides - Biochemicals and Reagents
  4. Peptide Synthesis 多肽合成
  1. Chemical Synthesis 化学合成
  2. Chemical Biology 生物化学
  3. Peptide Chemistry 多肽化学
  4. Amine Protection - Peptide Chemistry
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Protection and Derivatization - Synthetic Reagents
  4. Protecting and Derivatizing Reagents - Protection and Derivatization
  5. Others - Protecting and Derivatizing Reagents
  1. Functional Group 官能团索引
  2. carbonic acid monoester

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