Rubidium Hydroxide 氢氧化铷

CAS 1310-82-3 MFCD00011194

化学结构图

1310-82-3
SMILES: [OH-].[Rb+]

化学属性

Mol. FormulaRbOH
Mol. Weight102.48
Density1.74 g/mL at 25 °C
SolubilitySoluble in water, alcohol
TSCAYes
Melting Point300-302°C

别名和识别编码

Chemical NameRubidium Hydroxide
Synonym 氢氧化铷, 50% W/W AQ. SOLN., 99.6+% (METALS BASIS) rubidiumhydroxide(rb(oh)) Rubidium hydroxide hydrate, 99% (metals basis), 15-20% H2O Rubidium hydroxide, 50 wt. % solution in water, extra pure, 99.9% Rubidiumhydroxidehydrate,fusedsolid(99.8%-Rb) RUBIDIUM HYDROXIDE HYDRATE, FUSED SOLID: 99.8% RUBIDIUM HYDROXIDE MONOHYDRATE RUBIDIUM HYDROXIDE, 99.9%, CA. 50 WT. % SOLUTION IN WATER RUBIDIUM HYDROXIDE RUBIDIUM HYDROXIDE, 50% AQUEOUS SOLUTION RUBIDIUM HYDROXIDE HYDRATE FUSED SOLID (99.9%-RB) RUBIDIUM HYDROXIDE 99.9% 50% AQ. SOLN. Rubidium hydroxide, 50 wt. % solution in water, extra pure Rubidiumhydroxid Rubidium hydroxide, 50 wt. % solution in water, pure, 99% Rubidiumhydroxide,50%aqueoussolution(99+%-Rb) RUBIDIUM HYDR
MDL NumberMFCD00011194
CAS Number1310-82-3
PubChem Substance ID62393
EC Number215-186-0
Merck Number14,8285
Chemical Name Translation氢氧化铷
Wiswesser Line NotationRB Q
LabNetwork Molecule IDLN02144191
InChIInChI=1S/H2O.Rb/h1H2;/q;+1/p-1
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分类

  • {SNA} Acids & Bases, Bases, Chemical Synthesis, Essential Chemicals, Inorganic Bases, Materials Science, Metal and Ceramic Science, Research Essentials, Rubidium Salts, Salts, Synthetic Reagents
  • {uni_hamburg} no charge; 2fragments; ionic
  • {SNA} Chemical Synthesis, Inorganic Bases,

相关文献及参考

  • Short: II/24A Title: Molecular Constants mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy: Rotational, l-type, Centrifugal Distortion and Related Constants of Diamagnetic Diatomic, Linear, and Symmetric Top Molecules Author: Demaison, J.; Hübner, H.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/24A Year: 1998 Keyword: Diamagnetics Diatomics; Linear Symmetric Rotors; Molecular Constants; Molecules ISBN: 3-540-63267-0 ISBN: 978-3-540-63267-2 Internet Resource: DOI:10.1007/b60165 RefComment: VIII, 286 pages. Hardcover Abstract: Volume II/24 presents the spectroscopic data on diamagnetic and paramagnetic molecules as well as on molecular ions and radicals up to date considering the publications up to and partly including 1997. The spectroscopic information collected in this volume has been obtained principally from gas phase microwave measurements. Volume II/24 is a supplement to volumes II/4, II/6, II/14, and II/19 and is planned to appear in five subvolumes, the last of which will contain the substance index taking into account all molecules worked at since 1967 in the volumes mentioned and will provide cross references to and between all tables of these. The present subvolume II/24A contains the general introduction and tables of rotational and centrifugal distortion constants of diamagnetic diatomic, linear and symmetric-top molecules, i.e. data which roughly specifies the frequencies of the rotational transitions of these types of rotors.
  • Short: II/24C Title: Molecular Constants mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy: Dipole Moments, Quadrupole Coupling Constants, Hindered Rotation and Magnetic Interaction Constants of Diamagnetic Molecules Author: Demaison, J.; Hübner, H.; Hüttner, W.; Vogt, J.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/24C Year: 2002 Keyword: Atoms; Molecules and Cluster;

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H302+H312+H332
  • H332 Harmful if inhaled 吸入有害
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSVL8750000
Precautionary statements
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S20 When using do not eat or drink 使用时，不得进食，饮水；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
Packing GroupII
UN Number 2677 UN2678 UN 2677 8/PG 2 UN2677
Risk Statements
  • R34 Causes burns 会导致灼伤
  • R22 Harmful if swallowed 吞咽有害
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
Storage condition Hygroscopic
Hazard Codes C
Hazard Class8
Warnings 危化品目录(2015) 危险化学品 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 900 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   20PKA3 "Novye Dannye Po Toksikologii Redkikh Metalov Ikh Soedinenii," New
   Data on the Toxicology of Rare Metals and Their Compounds, Izrael'son, Z.I.,
   ed., Moscow, Izdatel'stvo "Meditsina," 1967  Volume(issue)/page/year:
   -,56,1967

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 586 mg/kg
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - respiratory stimulation
   Gastrointestinal - other changes
   Skin and Appendages - hair
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   32,239,1975

其他信息

  • 储运特性:库房通风低温干燥; 与酸、金属、氨盐、易燃物分开存放
  • 灭火剂:水、砂土
  • 氢氧化铷相关化学反应:氢氧化铷与镁在氢气流中加热时，则能生成金属铷和氧化镁，并放出氢气。 氢氧化铷与氯气作用，不加热时生成次氯酸铷;加热时则生成氯酸铷；均能同时生成氯化铷和水。 2RbOH+Cl2＝RbOCl+RbCl+H2O 6RbOH+3Cl2＝RbClO3+5RbCl+3H2O 氢氧化铷与酸发生中和反应，形成相应的铷盐和水。 氢氧化铷与氢氧化铝作用，则生成四羟基合铝(Ⅲ)酸铷. RbOH+Al(OH)3＝Rb[Al(OH)4] 在加热下，氢氧化铷与氯化铵作用，则生成氯化铷和水，并放出氨气. RbOH+NH4CL＝RbCl+NH3+H2O 氢氧化铷与金属氯化物反应，均生成氯化铷和相应的氢氧化物或氧化物. 氢氧化铷与酸性氧化物作用，则生成水和相应的铷盐. 2RbOH+CO2＝Rb2CO3+H2O 2RbOH+CrO3＝Rb2CrO4+H2O
  • 毒性分级:中毒
  • 类别:腐蚀物品
  • 强碱:氢氧化铷水溶液比氢氧化钾的碱性更强，是已知的第二强碱，只与酸反应，不与碱反应，化学式RbOH。分子量102.48。灰白色固体，常结为块状，有很强的吸水性，易潮解。比重3.203。熔点301±0.9℃。易溶于水。热的浓溶液能迅速地与镍和银反应。水溶液在铂皿中减压加热至400℃可脱水成无水物。其固体与溶液均能从空气中吸收二氧化碳。由硫酸铷与氢氧化钡反应而得。可在低温使用的蓄电池中作电极，氧化氯化反应的催化剂。 金属铷与水发生爆炸性的反应，生成氢氧化铷，并放出氢气。 碘化铷与氢氧化铷的混合溶液中通入氯气，加热后能生成氯化铷和碘酸铷结晶。 硫酸铷与氢氧化钡作用，生成氢氧化铷，并析出白色硫酸钡沉淀。 氢氧化铷和二氧化碳反应或由草酸铷或酒石酸氢铷加热分解而制得碳酸铷。 以上信息由Chemicalbook的彤彤编辑整理。
  • MSDS 信息:氢氧化铷(1310-82-3).msds
  • Sigma Aldrich:1310-82-3(sigmaaldrich)
  • 急性毒性:口服-大鼠 LD50: 586 毫克/公斤; 口服-小鼠 LD50: 900 毫克/公斤
  • 水中溶解度(g/100ml):每100毫升水中的溶解克数: 180g/20℃
  • MOL 文件:1310-82-3.mol
  • Alfa Aesar:氢氧化铷水合物,99%(metalsbasis),15-20%H{2}O Rubidium hydroxide hydrate, 99% (metals basis)(1310-82-3)
  • 图谱信息:氢氧化铷(1310-82-3)红外图谱(IR1)
  • 敏感性:Hygroscopic
  • 可燃性危险特性:遇水放出大量热助燃; 遇金属放出可燃氢气; 遇氨盐放出可燃氨气
  • Acros Organics:氢氧化铷 Rubidium hydroxide, 50 wt. % solution in water, extra pure, 99.9%(1310-82-3)
  • 氢氧化铷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 222810100 氢氧化铷 Rubidium hydroxide 99%, pure, 50 wt. % solution in water 10 GR 376元 2010/06/21 222990250 氢氧化铷 Rubidium hydroxide 99.9%, extra pure, 50 wt. % solution in water 25 GR 1418元 2010/06/21 222810500 氢氧化铷 Rubidium hydroxide 99%, pure, 50 wt. % solution in water 50 GR 1163元
  • 外观性质:灰白色易潮解的块状物。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Inorganic Acids - Synthetic Reagents
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Inorganic Bases - Synthetic Reagents
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Inorganic Bases - Synthetic Reagents
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Inorganic Salts - Synthetic Reagents
  4. Sodium - Inorganic Salts
  1. Materials Science 材料科学
  2. Metal and Ceramic Science Products 金属和陶瓷科学
  3. Salts 金属盐
  4. Rubidium Salts - Salts