(S)-(+)-1,1-Binaphthol-2,2-Bis(Trifluoromethanesulfonate) (S)-(+)-1,1-联-2-萘酚二(三氟甲磺酸酯)
CAS 128544-05-8 MFCD00274615
化学结构图
SMILES: O=S(=O)(Oc1ccc2ccccc2c1-c1c(OS(=O)(=O)C(F)(F)F)ccc2ccccc12)C(F)(F)F
化学属性
| Mol. Formula | (CF3SO3C10H6-)2 |
|---|---|
| Mol. Weight | 550.45 |
| Melting Point | 83-85 |
| Density | 1.422 |
别名和识别编码
| Chemical Name | (S)-(+)-1,1-Binaphthol-2,2-Bis(Trifluoromethanesulfonate) |
|---|---|
| Synonym | (S)-1,1′-二(2-萘酚)双(三氟甲磺酸酯) (S)-1,1′-联萘-2,2′-二基双(三氟甲磺酸酯) (S)-1,1′-二(2-萘酚)双(三氟甲磺酸酯) (S)-(+)-1,1′-二-2-萘酚双(三氟甲磺酸酯) (S)-1,1′-联萘-2,2′-二基双(三氟甲磺酸酯) |
| Beilstein Registry Number | 3579131 |
| PubChem Substance ID | 389883 |
| CAS Number | 128544-05-8 |
| MDL Number | MFCD00274615 |
| Reaxys-RN | 5466805 |
| EC Number | 250-023-7 |
| Chemical Name Translation | (S)-(+)-1,1-联-2-萘酚二(三氟甲磺酸酯) |
| InChI | InChI=1S/C22H12F6O6S2/c23-21(24,25)35(29,30)33-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)34-36(31,32)22(26,27)28/h1-12H |
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分类
- Asymmetric Synthesis, BINOLs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes
- {SNA} Asymmetric Synthesis, BINOLs, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Privileged Ligands and Complexes
产品应用
- 用于合成异双配位基配体（heterobidentate ligands），用于非对称催化。
相关文献及参考
- 1. J. Org. Chem. 58 , 1945, (1993)
- 2. Acta Chem. Scand. 50 , 259, (1996)
- FT-IR 2 (2), 3257:A / Structure Index 1 , 348:C:4
安全信息
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331
- P303+P361+P353+P310+P363
- P304+P340
- P305+P351+P338
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
GHS Symbol
- H290 May be corrosive to metals 可能腐蚀金属。
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- R34 Causes burns 会导致灼伤
