Bis(cyclopentadienyl)chromium(II) 双(环戊二烯)铬
CAS 1271-24-5 MFCD00013750
化学结构图
SMILES: [CH]1[CH][CH][CH][CH]1.[CH]1[CH][CH][CH][CH]1.[Cr]
化学属性
| Mol. Formula | Cr(C5H5)2 |
|---|---|
| Mol. Weight | 182.18 |
| Melting Point | 168-170 °C (lit.) |
| TSCA | Yes |
| Appearance | scarlet xtl. |
| Stability | air sensitive |
别名和识别编码
| Chemical Name | Bis(cyclopentadienyl)chromium(II) |
|---|---|
| Synonym | Bis(η5-cyclopentadienyl)chromium(II) Bis(cyclopentadiene)chromium(II) chromocene bis(cyclopentadienyl)chromium(II) 二茂铬 Chromium, di-pi-cyclopentadienyl- Chromium, dicyclopentadienyl- 双(环戊二烯)铬(II) Chromium, di-π-cyclopentadienyl- 二(环戊二烯基)铬(II) 二茂铬 Bis(eta(5)-cyclopentadienyl)chromium Chromocene, Di(cyclopentadienyl)chromium(II) bis(η5-cyclopenta-2,4-dien-1-yl)chromium 二(环戊二烯基)铬(II) Bis(cyclopentadiene)chromium Bis(cyclopentadienyl)chromium Di(η5-cyclopentadienyl)chromium Dicyclopentadienylchromium Di((eta-5)-cyclopentadienyl)chromium Bis(cyclopentadienyl)chromium(II) |
| MDL Number | MFCD00013750 |
| PubChem Substance ID | 24863782 |
| CAS Number | 1271-24-5 |
| EC Number | 215-036-4 |
| Chemical Name Translation | 双(环戊二烯)铬 |
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分类
- {SNA} CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Chromium, Chromium Catalysts, Micro/NanoElectronics, Vapor Deposition Precursors, 材料科学
- {SNA} CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Chromium, Materials Sci
相关文献及参考
- Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source
- Short: II/25D Title: Structure Data of Free Polyatomic Molecules: Molecules Containing Five or More Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25D Year: 2003 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-42860-7 ISBN: 978-3-540-42860-2 Internet Resource: DOI:10.1007/b75952 RefComment: VIII, 569 pages. Hardcover RefComment: Written for scientists and researchers in the fields of chemistry and physics Abstract: This fourth subvolume presents data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc) of free polyatomic molecules including free radicals and molecular ions. The survey on structure data consists of four subvolumes, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this fourth subvolume, the structure of molecules containing five to sixty carbon atoms is listed.
- Short: IV/8A Title: Enthalpies of Fusion and Transition of Organic Compounds Author: Zhang, Z.-Y.; Frenkel, M.; March, K.N.; Wilhoit, R.C. Editor: Marsh, K.N. Source: Landolt-Börnstein, New Series Volume: IV/8A Year: 1995 Keyword: organic compounds; enthaly of fusion; melting point; phase transition ISBN: 3-540-58854-X ISBN: 978-3-540-58854-2 Internet Resource: DOI:10.1007/b55145 RefComment: VIII, 588
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P305+P351+P338
- H332 Harmful if inhaled 吸入有害
- H315 Causes skin irritation 会刺激皮肤
- H302 Harmful if swallowed 吞食有害
- H312 Harmful in contact with skin 皮肤接触有害
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H319 Causes serious eye irritation 严重刺激眼睛
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S33 Take precautionary measures against static discharges 对静电采取预防措施；
- S8 Keep container dry 保持容器干燥；
- S30 Never add water to this product 切勿将水加入该产品中；
- S37 Wear suitable gloves 戴适当手套；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R17 Spontaneously flammable in air 在空气中能够自燃
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
TYPE OF TEST : Mutation in microorganisms TEST SYSTEM : Bacteria - Salmonella typhimurium DOSE/DURATION : 1 mg/plate REFERENCE : EMMUEG Environmental and Molecular Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.10- 1987- Volume(issue)/page/year: 19(Suppl 21),2,1992
