(Acetylacetonato)(1,5-Cyclooctadiene)Rhodium(I) 1,5-环辛二烯(乙酰丙酮)铑(I)
CAS 12245-39-5 MFCD00075046
化学结构图
SMILES: C/C(=C/C(C)=O)/O[Rh].C1CC=CCCC=C1
化学属性
| Mol. Formula | C13H19O2Rh |
|---|---|
| Mol. Weight | 310.19 |
| Melting Point | 138-140 °C(lit.) |
| TSCA | No |
| Appearance | orange xtl. |
| Stability | air sensitive, store cold |
别名和识别编码
| Chemical Name | (Acetylacetonato)(1,5-Cyclooctadiene)Rhodium(I) |
|---|---|
| Synonym | Rh(acac)(COD) 1,5-环辛二烯(乙酰丙酮)铑(I) (1,5-Cyclooctadiene)(2,4-pentanedionato)rhodium Acetylacetonate-1,5-cyclooctadiene rhodium (Acetylacetonato)(1,5-cyclooctadiene)rhodium(I) Rhodium, ((1,2,5,6-eta)-1,5-cyclooctadiene)(2,4-pentanedionato-O,O')- 乙酰丙酮(1,5-环辛二烯)铑 |
| MDL Number | MFCD00075046 |
| PubChem Substance ID | 329760794 |
| CAS Number | 12245-39-5 |
| Chemical Name Translation | 1,5-环辛二烯(乙酰丙酮)铑(I) |
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分类
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Rhodium Catalysts
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Rhodium
- {SNA} CVD and ALD Precursors by Metal, Catalysis and Inorganic Chemistry, Chemical Synthesis, Micro/NanoElectronics, Rhodium, Vapor Deposition Precursors, 材料科学
相关文献及参考
- FT-IR 2 (3), 4529:A / FT-NMR 1 (3), 754:B / RegBook 1 (2), 3091:B / Structure Index 1 , 489:E:7
安全信息
GHS Symbol
- P305+P351+P338
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S37 Wear suitable gloves 戴适当手套；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 34 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : CBINA8 Chemico-Biological Interactions. (Elsevier Scientific Pub. Ireland Ltd., POB 85, Limerick, Ireland) V.1- 1969- Volume(issue)/page/year: 45,1,1983
