CAS 122-66-7 MFCD00003012-Hydrazobenzene 二苯肼 TAO{mole}

Hydrazobenzene 二苯肼

CAS 122-66-7 MFCD00003012

化学结构图

SMILES: c1ccc(NNc2ccccc2)cc1

化学属性

Mol. Formula	C12H12N2
Mol. Weight	184
Melting Point	125.0 to 128.0 deg-C
TSCA	Yes
Solubility	不溶于水、乙酸，微溶于苯，易溶于乙醇。
Density	1.158

别名和识别编码

Chemical Name	Hydrazobenzene
Synonym	SYM-DIPHENYLHYDRAZINE N,N'-Diphenyl-hydrazine 1,2-二苯基肼 Hydrazobenzol hydrazodi-benzen 二苯肼 hydrazobenzene(1,2-diphenylhydrazine) 1,2-Diphenylhydrazine Benzene, 1,1'-hydrazobis- N,N'-Bianiline N,N'-Bianiline 1,2-DIPHENYLHYDRAZINE N,N'-biphenylhydrazine N,N'-diphenylhydrazine RCRA waste number U109 1,2-二苯肼 N,N'-Bianiline NSC 3510 Hydrazodibenzene N,N'-Diphenylhydrazine hydrazobenzene 1,2-DIPHENYLDIAZANE (sym)-Diphenylhydrazine N,N′-Bianiline 氢化偶氮苯肼撑苯 Hydrazobenzen 1,2-二苯基联氨 1,1’-hydrazobis-benzen hydrazobenzen(czech) hydrazine, 1,2-diphenyl- HYDRAZOBENZENE N,N'-diphenyl-hydrazine n,n’-bianiline sym-diphenylhydrazine NCI-C01854 1,2-二苯肼 hydrazine,1,2-diphenyl-
Beilstein Registry Number	15(3)76
PubChem Substance ID	31222
CAS Number	122-66-7
EC Number	204-563-5
MDL Number	MFCD00003012
Reaxys-RN	639793
Chemical Name Translation	二苯肼
Wiswesser Line Notation	RMMR
LabNetwork Molecule ID	LN00336934
InChI	InChI=1S/C12H12N2/c1-3-7-11(8-4-1)13-14-12-9-5-2-6-10-12/h1-10,13-14H

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安全信息

Precautionary statements

P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P501 Dispose of contents/container to..… 处理内容物/容器.....
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P308+P313
P273 Avoid release to the environment. 避免释放到环境中。
P201 Obtain special instructions before use. 使用前获取专门指示。
P405 Store locked up. 上锁保管。
P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
P301+P312+P330
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。

RTECSMW2625000

WGK Germany3

GHS Symbol

Signal word

Hazard statements

H302 Harmful if swallowed 吞食有害
H350 May cause cancer 可能致癌
H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。

Hazard Codes T,N

Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges dust mask type N95 (US), Eyeshields, Gloves, type P2 (EN 143) respirator cartridges

UN Number UN3077 UN 3077 9/PG 3 3077

Storage condition 0-10 0-10°C Refrigerator

Safety Statements

S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；

Risk Statements

R45 May cause cancer 可能致癌
R22 Harmful if swallowed 吞咽有害
R50/53

Packing GroupIII

Hazard Class9

Warnings 危化品目录(2015)

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 16 gm/kg/1Y-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Sense Organs and Special Senses (Ear) - effect, not otherwise specified
REFERENCE :
   CANCAR Cancer (Philadelphia).  (Lippincott/Harper, Journal Fulfillment
   Dept., 2350 Virginia Ave., Hagerstown, MD 21740)  V.1-    1948-
   Volume(issue)/page/year: 3,789,1950

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 9820 mg/kg/78W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Liver - tumors
   Skin and Appendages - tumors
REFERENCE :
   NCITR* National Cancer Institute Carcinogenesis Technical Repor

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 5280 mg/kg/26W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Liver - tumors
REFERENCE :
   VOONAW Voprosy Onkologii.  Problems of Oncology.  For English translation,
   see PONCAU. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-10,
   1928-37; V.1-    1955-  Volume(issue)/page/year: 20(4),53,1974

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 36 gm/kg/53W-I
TOXIC EFFECTS :
   Tumorigenic - equivocal tumorigenic agent by RTECS criteria
   Skin and Appendages - tumors
   Reproductive - Tumorigenic effects - uterine tumors
REFERENCE :
   VOONAW Voprosy Onkologii.  Problems of Oncology.  For English translation,
   see PONCAU. (V/O Mezhdunarodnaya Kniga, 113095 Moscow,

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 14 mg/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   10(Suppl 10),1,1987

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Ovary
DOSE/DURATION           : 5 mg/L
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   10(Suppl 10),1,1987

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 10 ng/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 7(Suppl
   5),1,1985

TYPE OF TEST            : DNA inhibition
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 100 mg/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 46,305,1977

Restrict 危险品

其他信息

上游原料:锌粉 --> 硅
MOL 文件:122-66-7.mol
可燃性危险特性:明火可燃;与氧化剂起作用; 高热分解有毒氮氧化物烟雾
1,2-二苯肼价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 H0180 二苯肼 Hydrazobenzene 25G 422元 2014/06/02 H0180 二苯肼 Hydrazobenzene 100G 1300元 2010/05/25 A18037 苯肼, tech. 86% Hydrazobenzene, tech. 90%, remainder mainly azobenzene 25g 399元
图谱信息:1,2-二苯肼(122-66-7)质谱(MS)
下游产品:联苯胺 --> 颜料黄 12 --> 分散黄RGFL --> 保泰松
用途一:用作有机合成原料，也用于制解热止痛类药物保太松
方法一:由硝基苯经还原得到的二苯肼有两种方法。1.用锌粉还原；2.用葡萄糖和硅粉还原。
用途二:医药工业用于生产解热镇痛药保泰松；染料工业用于制造联苯胺染料等。
F:10-23
灭火剂:泡沫、雾状水、二氧化碳、砂土
Alfa Aesar:苯肼,tech.86% Hydrazobenzene, 95%, remainder mainly azobenzene(122-66-7)
储运特性:库房通风低温干燥; 与氧化剂、食品添加剂、酸类分开存放
TCI Shanghai:1,2-二苯基肼 Hydrazobenzene,>;98.0%(LC)(122-66-7)
MSDS 信息:1,2-二苯肼(122-66-7).msds
Sigma Aldrich:122-66-7(sigmaaldrich)
外观性质:片状结晶。
类别:有毒物品