CAS 120-54-7 MFCD00047474-Tetrasulfanediylbis(piperidin-1-ylmethanethione) 1,1’-(四硫代二碳硫基)双哌啶 TAO{mole}

Tetrasulfanediylbis(piperidin-1-ylmethanethione) 1,1’-(四硫代二碳硫基)双哌啶

CAS 120-54-7 MFCD00047474

化学结构图

SMILES: S=C(SSSSC(=S)N1CCCCC1)N1CCCCC1

化学属性

Mol. Formula	C12H20N2S6
Mol. Weight	385
Appearance	四硫化双五亚甲基秋兰姆(120-54-7)为白色或灰黄色粉末。熔点115℃，相对密度1.50。溶于二硫化碳、氯仿和四氯化碳，不溶于水。
Melting Point	118.0 to 122.0 deg-C

别名和识别编码

Chemical Name	Tetrasulfanediylbis(piperidin-1-ylmethanethione)
MDL Number	MFCD00047474
CAS Number	120-54-7
Reaxys-RN	298051
PubChem Substance ID	87566977
EC Number	204-406-0
Synonym	1,1'-(Tetrathiodicarbonothioyl)-bis-piperidine 1,1'-(tetrathiodicarbonothioyl)-bis-piperidine 1,1’-(tetrathiodicarbonothioyl)bis-piperidin 1,1’-(四硫代二碳硫基)双哌啶 Accelerator DPTT Accelerator(tra) BIS(PENTAMETHYLENETHIOCARBAMOYL) TETRASULFIDE BIS(PIPERIDINOTHIOCARBONYL) TETRASULFIDE Bis(pentamethylene)thiuram tetrasulfide Bis(pentamethylenethiuram)-tetrasulfide Bis(piperidinothiocarbonyl) tetrasulfide DIPENTAMETHYLENETHIURAM TETRASULFIDE DPTT Dipentamethylenethiram Tetrasulfide Dipentamethylenethiuram tetrasulfide Nocceler TRA Soxinol TRA Sulfads Tetrasulfide, bis(pentamethylenethiuram)- Tetron A Tetrone A Thiuram MT Thiuram tetrasulfide, bis(piperidinothiocarbonyl) USAF B-31 bis(pentamethylenethiuram)-tetrasulfid noccelertra sancelertra soxinoltra tetrasulfide,bis(piperidinothiocarbonyl) tetrona tetronea thiurammt thiuramtetrasulfide,bis(piperidinothiocarbonyl) usafb-31 二哌啶基秋兰姆-硫化物促进剂 TRA 促进剂DPTT 促进剂TRA 四硫化双五亚甲基秋兰姆四硫化双五亚甲基秋蓝姆四硫化双五甲亚基秋兰姆四硫化双五甲撑秋兰姆四硫化双硫羰基五亚甲胺四硫化雙(五亞甲硫醯胺基) 四硫化雙(五亞甲胺硫醯基) 四硫化雙五亞甲硫醯胺基橡胶促进剂 DPTT 母胶粒DPTT-70 母胶粒TRA-70 药胶DPTT-7O 药胶TRA-7O 预分散TRA-70
Chemical Name Translation	1,1’-(四硫代二碳硫基)双哌啶
Wiswesser Line Notation	T6NTJ AYUS&SS 2
Beilstein Registry Number	0298051
LabNetwork Molecule ID	LN00201703

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安全信息

RTECSTN4221000

Signal word

Hazard statements

H411 Toxictoaquaticlifewithlonglastingeffects 对水生生物有毒性并具有长期影响。
H317 May cause an allergic skin reaction 可能导致皮肤过敏

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P302+P352+P333+P313+P362+P364
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P501 Dispose of contents/container to..… 处理内容物/容器.....
P333+P313
P302+P350
P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
P273 Avoid release to the environment. 避免释放到环境中。
P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。

Safety Statements

S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；

Risk Statements

R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
R51/53

GHS Symbol

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD277-689

WGK Germany2

Hazard Codes N

其他信息

用途一:用作天然、丁苯、丁腈、丁基、氯丁、异戊二烯、氯磺化聚乙烯等橡胶的促进剂
MOL 文件:120-54-7.mol
方法一:由六氢吡啶、碳酸钠和二硫化碳反应制得五亚甲基二硫代氨基甲酸钠，再用一氯化硫处理即得四硫化双五亚甲基秋蓝姆。
图谱信息:四硫化双五亚甲基秋兰姆(120-54-7)核磁图( 13 CNMR) 四硫化双五亚甲基秋兰姆(120-54-7)红外图谱(IR1) 四硫化双五亚甲基秋兰姆(120-54-7)红外图谱(IR2) 四硫化双五亚甲基秋兰姆(120-54-7)质谱(MS)
上游原料:过氧化氢 --> 二硫化碳 --> 六氢吡啶 --> 二氯化二硫 --> 甲基二硫代氨基甲酸钠
用途二:本品为秋蓝姆类硫化促进剂，可用于天然橡胶、二烯类合成橡胶、丁基橡胶、三元乙丙橡胶、氯磺化聚乙烯和胶乳。加热能分解出游离硫，亦可作为硫化剂，有效含硫量为其重量的25%。本品作硫化剂时在操作温度下比较安全，硫化胶耐热、耐老化性能优良。本品易分散于干橡胶中，亦易分散于水中。不污染。一般用于制造耐热制品、电缆等。
四硫化双五亚甲基秋兰姆价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 D0279 四硫化二五亚甲基秋兰姆(俗称)[硫化加速剂] Dipentamethylenethiuram Tetrasulfide (so called) [Vulcanization Accelerator] 500G 1830元 2014/06/02 D0279 四硫化二五亚甲基秋兰姆(俗称)[硫化加速剂] Dipentamethylenethiuram Tetrasulfide (so called) [Vulcanization Accelerator] 25G 218元
TCI Shanghai:二哌啶基秋兰姆-硫化物(俗称)[硫化加速剂] Dipentamethylenethiuram Tetrasulfide (so called) [Vulcanization Accelerator](120-54-7)