2-Isonitrosopropiophenone 2-异亚硝基苯丙酮
CAS 119-51-7 MFCD00002115
化学结构图
SMILES: C/C(=N\O)C(=O)c1ccccc1
化学属性
| Mol. Formula | C9H9NO2 |
|---|---|
| Mol. Weight | 163.17 |
| Melting Point | 113-115 °C |
| Density | 1.422 |
| Boiling Point | 290.25 °C at 760 mmHg |
别名和识别编码
| Chemical Name | 2-Isonitrosopropiophenone |
|---|---|
| Synonym | 2-(Hydroxyimino)-1-phenylpropan-1-one {LY} 2-(Hydroxyimino)-1-phenylpropan-1-one {} {LY} 2-(Hydroxyimino)-1-phenylpropan-1-one {} {} {LY} 2-(Hydroxyimino)-1-phenylpropan-1-one {} {} {} {LY} 2-(Hydroxyimino)-1-phenylpropan-1-one {} {} {} {} {LY} 2-(Hydroxyimino)-1-phenylpropan-1-one {} {} {} {} {} {LY} 2-(Hydroxyimino)-1-phenylpropan-1-one {} {} {} {} {} {} {LY} 2-(Hydroxyimino)-1-phenylpropan-1-one {} {} {} {} {} {} {} {LY} 2-(Hydroxyimino)-1-phenylpropan-1-one {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {LY} 2-(Hydroxyimino)-1-phenylpropan-1-one {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Hydroxyimino)-1-phenylpropan-1-one {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} 2-(Hydroxyimino)-1-phenylpropan-1-one {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Hydroxyimino)-1-phenylpropan-1-one {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Hydroxyimino)-1-phenylpropan-1-one {} {} {} {} {} {} {} {} |
| MDL Number | MFCD00002115 |
| PubChem Substance ID | 87574457 |
| CAS Number | 119-51-7 |
| EC Number | 204-329-2 |
| Beilstein Registry Number | 509304 |
| Reaxys-RN | 509304 |
| Chemical Name Translation | 2-异亚硝基苯丙酮 |
| Wiswesser Line Notation | QNUY1&VR |
| InChIKey | YPINLRNGSGGJJT-JXMROGBWSA-N |
| Canonical SMILES | CC(=NO)C(=O)C1=CC=CC=C1 |
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分类
- {SNA} Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Oximes
- Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Oximes
相关文献及参考
- 1. E. Baranoff, et al., , Cyclometalated Iridium(III) Complexes Based on Phenyl-Imidazole Ligand Inorg. Chem. 50 , 451-462, (2011)
- 2. M. Jasinski, et al., , Synthesis of 2,3-dihydroimidazo[2,1-b]thiazole derivatives via cyclization of N-allylimidazoline-2-thiones J. Heterocycl. Chem. 47 , 1287-1293, (2010)
- 3. M. Bakherad, et al., , Copper- and solvent-free Sonogashira coupling reactions of aryl halides with terminal alkynes catalyzed by 1-phenyl-1,2-propanedione-2-oxime thiosemicarbazone-functionalized polystyrene resin supported Pd(II) complex under aerobic conditions Appl. Catal. 390 , 135-140, (2010)
- 4. P. Kwiatkowski, et al., , Novel chiral C2-symmetric bisimidazole-N-oxides as promising organocatalysts for enantioselective allylation of aromatic aldehydes Synlett 11 , 1757-1760, (2009)
- 5. B. N. H. Kumar, et al., , Beckmann rearrangement of a-oximinoketones Indian J. Chem. B 47B , 963-965, (2008)
- 6. L. A. Holowatz, et al., , Oral atorvastatin therapy restores cutaneous microvascular function by decreasing arginase activity in hypercholesterolaemic humans J. Physiol. 589 , 2093-2103, (2011)
- Beil. 7 ,III,3464
- FT-IR 2 (3), 4008:D / FT-IR 1 (2), 924:D / FT-NMR 1 (3), 491:C / IR-Spectra (3), 1428:G / NMR-Reference 2 (2), 972:D / RegBook 1 (2), 2689:F / Sigma FT-IR 1 (2), 668:D / Structure Index 1 , 423:D:5
安全信息
- H303 May be harmfully swallowed 吞食可能有害
- P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
GHS Symbol
- S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Administration onto the skin SPECIES OBSERVED : Rodent - rabbit DOSE/DURATION : >4 gm/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 28,313,1974
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Oral SPECIES OBSERVED : Rodent - rat DOSE/DURATION : 4240 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 28,313,1974
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill ROUTE OF EXPOSURE : Intraperitoneal SPECIES OBSERVED : Rodent - mouse DOSE/DURATION : 250 mg/kg TOXIC EFFECTS : Details of toxic effects not reported other than lethal dose value REFERENCE : NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD691-490
其他信息
- 2-异亚硝基苯丙酮价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 P0211 2-异亚硝基苯丙酮 2-Isonitrosopropiophenone 25G 644元 2010/06/21 205020250 2-异亚硝基苯丙酮 1-Phenyl-1,2-propanedione-2-oxime 99% 25 GR 720元 2010/06/21 205020100 2-异亚硝基苯丙酮 1-Phenyl-1,2-propanedione-2-oxime 99% 10 GR 408元
- Acros Organics:1-苯基-1，2-丙二酮-2-肟 1-Phenyl-1,2-propanedione-2-oxime, 99%(119-51-7)
- MSDS 信息:1-Phenyl-1,2-propanedione-2-oxime(119-51-7).msds
- MOL 文件:119-51-7.mol
- 图谱信息:2-异亚硝基苯丙酮(119-51-7)质谱(MS) 2-异亚硝基苯丙酮(119-51-7)核磁图( 1 HNMR) 2-异亚硝基苯丙酮(119-51-7)Raman光谱 2-异亚硝基苯丙酮(119-51-7)核磁图( 13 CNMR) 2-异亚硝基苯丙酮(119-51-7)红外图谱(IR2) 2-异亚硝基苯丙酮(119-51-7)红外图谱(IR1)
- TCI Shanghai:1-苯基-1,2-丙二酮肟 2-Isonitrosopropiophenone,>;98.0%(GC)(119-51-7)
- Sigma Aldrich:119-51-7(sigmaaldrich)
- 海关编码:29280090
