Dimethylaluminum Chloride 二甲基氯化铝
CAS 1184-58-3 MFCD00000458
化学结构图
SMILES: C[AlH3](C)Cl
化学属性
| Mol. Formula | (CH3)2AlCl |
|---|---|
| Mol. Weight | 92.50 |
| Density | 0.701 g/mL at 25 °C |
| Melting Point | -21 °C(lit.) |
| Boiling Point | 126-127 °C(lit.) |
| Vapor Pressure | 79 mmHg ( 60 °C) |
别名和识别编码
| Chemical Name | Dimethylaluminum Chloride |
|---|---|
| Synonym | 二甲基氯化铝 溶液 dimethylaluminium chloride Aluminum, dimethyl-, chloride Dimethylaluminum chloride; Dimethylchloralane; Dimethylchloroalane; Dimethylchloroaluminum Chlorodimethylaluminum Dimethylaluminiumchlorid Chlordimethylaluminium Dimethylchloroalane Dimethylaluminum chloride 二甲基氯化铝 Dimethylchloroaluminum Dimethylchloralane Aluminum, chlorodimethyl- Dimethyl aluminum chloride Dimethylchloraluminium |
| MDL Number | MFCD00000458 |
| CAS Number | 1184-58-3 |
| PubChem Substance ID | 79147 |
| EC Number | 214-668-8 |
| Beilstein Registry Number | 2384789 |
| Chemical Name Translation | 二甲基氯化铝 |
| InChI | InChI=1S/2CH3.Al.ClH/h2*1H3;;1H/q;;+1;/p-1 |
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分类
- {uni_hamburg} no charge; metal-organic; 1fragment
- {SNA} Chemical Synthesis, Organoaluminum, Organometallic Reagents
相关文献及参考
- Short: III/31a Title: Nuclear Quadrupole Resonance Spectroscopy Data: Nuclei D ... Cu Author: Chihara, H.; Nakamura, N. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/31a Year: 1993 Keyword: NQR ISBN: 3-540-55146-8 ISBN: 978-3-540-55146-1 Internet Resource: DOI:10.1007/b43999 RefComment: VIII, 437 pages. Hardcover Abstract: Volume III/31 continues the compilation of nuclear quadrupole resonance spectroscopy data of solid substances which started in with volume III/20 in 1987 covering the literature from the beginning of nuclear quadrupole resonance spectroscopy in 1951 to 1982 and containing the data for 8000 substances in the solid state, distributed among three subvolumes III/20 a, b, and c. Volume III/31 covers the literature published in the period from the end of 1982 through the end of 1989. Included are the data for substances studied for the first time, as well as data for substances already present in the previous volume III/20 if the data published there could be completed or improved by new studies. In total there are 2500 substances in volume III/31, showing the scope and significance of nuclear quadrupole resonance spectroscopy up to recent times.
- Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
安全信息
- P301+P310
- P331 Do NOT induce vomiting.. 不要催吐。
- P273 Avoid release to the environment. 避免释放到环境中。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P302+P352
- P222 Do not allow contact with air. 不要与空气接触。
- P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能，因为会剧烈反应可能产生闪火。
- P422 Store contents under… 存储目录在…之下。
- P231+P232
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P370+P378
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体，可自燃。
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
GHS Symbol
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染；
- S29 Do not empty into drains 不要排入下水道；
- S6 Keep under ... (inert gas to be specified by the manufacturer) 将该物质保存在生产厂家指定的惰性气体中；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入，皮肤接触及吞食都有毒
- R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应，释放出高度可燃气体
- R17 Spontaneously flammable in air 在空气中能够自燃
- R34 Causes burns 会导致灼伤
- R11 Highly flammable 非常易燃
- R35 Causes severe burns 会导致严重灼伤
- R50/53
- R65 Harmful: may cause lung damage if swallowed 若吞咽可能伤害肺部器官
- R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
