CAS 114-83-0 MFCD00008672-1-Acetyl-2-Phenylhydrazine N-乙酰苯肼 TAO{mole}

1-Acetyl-2-Phenylhydrazine N-乙酰苯肼

CAS 114-83-0 MFCD00008672

化学结构图

SMILES: CC(=O)NNc1ccccc1

化学属性

Mol. Formula	C8H10N2O
Mol. Weight	150.18
Melting Point	128-131°C
TSCA	Yes
Density	1.143
Solubility	溶于热水、醇，微溶于醚。
Stability	对光敏感
Boiling Point	214.1ºC at 760 mmHg

别名和识别编码

Chemical Name	1-Acetyl-2-Phenylhydrazine
MDL Number	MFCD00008672
CAS Number	114-83-0
PubChem Substance ID	8247
EC Number	204-055-3
Synonym	N'-Phenylacetohydrazide {LY} N'-Phenylacetohydrazide {} {LY} N'-Phenylacetohydrazide {} {} {LY} N'-Phenylacetohydrazide {} {} {} {LY} N'-Phenylacetohydrazide {} {} {} {} {LY} N'-Phenylacetohydrazide {} {} {} {} {} {LY} N'-Phenylacetohydrazide {} {} {} {} {} {} {LY} N'-Phenylacetohydrazide {} {} {} {} {} {} {} {LY} N'-Phenylacetohydrazide {} {} {} {} {} {} {} {} {LY} N'-Phenylacetohydrazide {} {} {} {} {} {} {} {} {} {LY} N'-Phenylacetohydrazide {} {} {} {} {} {} {} {} {} {} {LY} N'-Phenylacetohydrazide {} {} {} {} {} {} {} {} {} {} {} {LY} N'-Phenylacetohydrazide {} {} {} {} {} {} {} {} {} {} {} {} {LY} N'-Phenylacetohydrazide {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N'-Phenylacetohydrazide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N'-Phenylacetohydrazide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N'-Phenylacetohydrazide {} {} {} {} {} {} {} {} {} {} {} {} {}
Beilstein Registry Number	742880
Chemical Name Translation	N-乙酰苯肼
Reaxys-RN	742880
Wiswesser Line Notation	1VMMR
LabNetwork Molecule ID	LN00238551
InChI	InChI=1S/C8H10N2O/c1-7(11)9-10-8-5-3-2-4-6-8/h2-6,10H,1H3,(H,9,11)
Canonical SMILES	CC(NNC1=CC=CC=C1)=O

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

产品应用

有机合成。稳定剂。

安全信息

WGK Germany3

GHS Symbol

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P310
P301+P310+P330
P305+P351+P338
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Danger

Hazard statements

H301 Toxic if swallowed 吞食有毒
H315 Causes skin irritation 会刺激皮肤
H317 May cause an allergic skin reaction 可能导致皮肤过敏
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激

RTECSAJ2900000

Personal Protective Equipment dust mask type N95 (US), Eyeshields, Faceshields, Gloves

Safety Statements

S22 Do not breathe dust 不要吸入粉尘；
S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36 Wear suitable protective clothing 穿戴适当的防护服；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；

Packing GroupIII

UN Number 2811 UN 2811 6.1/PG 3

Risk Statements

R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
R22 Harmful if swallowed 吞咽有害
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应

Hazard Codes 6.1 Xn

Storage condition 2-8°C {LY} 2-8°C Store at room temperature {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°

Hazard Class6.1

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 31 gm/kg/79W-I
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Vascular - tumors
   Lungs, Thorax, or Respiration - tumors
REFERENCE :
   BJCAAI British Journal of Cancer.  (Macmillan Press Ltd., Houndmills,
   Basingstoke, Hants. RG21 2XS, UK)  V.1-    1947-  Volume(issue)/page/year:
   39,584,1979

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 150 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: AD691-490

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 270 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   PCJOAU Pharmaceutical Chemistry Journal (English Translation).  Translation
   of KHFZAN. (Plenum Pub. Corp., 233 Spring St., New York, NY 10013)  No.1-
   1967-  Volume(issue)/page/year: 14,162,1980

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 333 ug/plate
REFERENCE :
   EMMUEG Environmental and Molecular Mutagenesis.  (Alan R. Liss, Inc., 41 E.
   11th St., New York, NY 10003)  V.10-    1987-  Volume(issue)/page/year:
   11(Suppl 12),1,1988

其他信息

MOL 文件:114-83-0.mol
Alfa Aesar:N-乙酰-N‘-苯肼,98% N-Acetyl-N'-phenylhydrazine, 98%(114-83-0)
储运特性:库房通风低温干燥
灭火剂:干粉、泡沫、砂土、二氧化碳, 雾状水
毒性分级:高毒
类别:有毒物品
方法一:由苯肼和乙酸反应。将苯肼，乙酸，水加热6h，趁热倒出，冷至0℃以下，过滤得粗品，用水重结晶，80℃干燥而得。
用途一:用于制药及有机合成工业
TCI Shanghai:乙酰苯肼 1-Acetyl-2-phenylhydrazine,>;98.0%(N)(114-83-0)
用途三:有机合成。稳定剂。
1-乙酰基-2-苯基肼价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 30003226 N-乙酰苯肼;乙酰基苯联氨 100g 51.9元 2011/08/23 30003260 N-乙酰苯肼;乙酰基苯联氨 100g 50元 2011/04/16 A0107 1-乙酰-2-苯肼 1-Acetyl-2-phenylhydrazine 25G 349元
急性毒性:口服-小鼠 LD50: 270 毫克/公斤; 腹腔-小鼠 LDL0: 150 毫克/公斤
用途二:有机中间体。稳定剂。
Sigma Aldrich:114-83-0(sigmaaldrich)
MSDS 信息:乙酰苯肼(114-83-0).msds
海关编码:29280090
易溶于乙醇，微溶于乙醚、冷水。热水中溶解度稍大些
图谱信息:1-乙酰基-2-苯基肼(114-83-0)核磁图( 1 HNMR) 1-乙酰基-2-苯基肼(114-83-0)质谱(MS) 1-乙酰基-2-苯基肼(114-83-0)核磁图( 13 CNMR) 1-乙酰基-2-苯基肼(114-83-0)Raman光谱 1-乙酰基-2-苯基肼(114-83-0)红外图谱(IR1) 1-乙酰基-2-苯基肼(114-83-0)红外图谱(IR2)
Acros Organics:N-乙酰苯肼 1-Acetyl-2-phenylhydrazine, 98%(114-83-0)
外观性质:灰白色粉末。
可燃性危险特性:可燃; 加热分解释放有毒氮氧化物烟雾